Study on Primary Reaction Kinetics of Melamine Aminated Monomethoxylpoly (ethylene Glycol)

Zhen Li; Yan Ding; Jin Liu

doi:10.4028/www.scientific.net/AMR.450-451.374

Paper Titles

Application of Nanomaterials in Interior Decoration
p.356

Stability Study of Chitosan-g-AM Inverse Emulsion
p.360

Effect of Fiber Volume Fraction on Fatigue Crack Propagation Rate of UHTCC
p.364

Failure Predictions of Laminate under In-Plane Tensile Loading
p.370

Study on Primary Reaction Kinetics of Melamine Aminated Monomethoxylpoly (ethylene Glycol)
p.374

Dynamic Constitutive Model of Concrete
p.379

Experimental Study on Mix Proportion of Fair-Faced Concrete for Urban Bridge
p.383

Sound Insulation Provided by PET Fabric/PVC Composite Materials
p.387

̅̅Research on Calcination Condition of Alite-Rich Portland Cement Clinker with C_2.75B_1.25A_{3 S}
p.392

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 450-451Study on Primary Reaction Kinetics of Melamine...

Study on Primary Reaction Kinetics of Melamine Aminated Monomethoxylpoly (ethylene Glycol)

Abstract:

The reaction kinetics of amination of monomethoxylpoly (ethylene glycol) (mPEG) with melamine (MA) at the molar ratio of 1:1 was studied by FTIR. This amination reaction was carried out with potassium hydroxide as reaction catalyst under high-pressure conditions at different temperature (160 °C, 170 °C, 180 °C, and 190°C) for different time (2 h, 3 h, 4 h, 5 h and 6 h). A series of melamine aminated monomethoxylpoly (ethylene glycol) (MA-mPEG) were synthesized, and the long chain of polyethylene glycol ether was grafted on the amino groups of melamine by amination. The amination kinetics parameter of reaction order and the activation energy are about 1.5 and 45 KJ/mol, respectively. In addition, the grafting amination yield increased with the number average molecular weight of mPEG at the same reaction condition.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 450-451)

Pages:

374-378

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.450-451.374

Citation:

Cite this paper

Online since:

January 2012

Authors:

Zhen Li, Yan Ding, Jin Liu

Keywords:

Amination, FT-IR, Melamine, Monomethoxylpoly (Ethylene Glycol), Reaction Kinetics

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Francis A. Bonzagni: [P].U.S. patent.(1958), 2, 863, 842

Google Scholar

[2] Qiu X. Q., Yi C. H, Yang D: J Modern Chem Ind. Vol.22 (2002), p.24

Google Scholar

[3] Wu Z. Q., Zeng F. S., Liu C.Y., Li W. N: Polym Mater Sci & Engi. Vol.14(1998), p.103

Google Scholar

[4] Xu D. R., Jia X. H., Ji A. S., Chen S. D: Shanxi Chemical Industry. Vol. 20(2000), p.4

Google Scholar

[5] Qiu S. H., Li Z. C., Liao X. H., Feng X: Industrial Construction. Vol. 36(2006), p.871

Google Scholar

[6] A. Baiker: Catal. Rev. Sci. Eng. Vol. 27 (1985), p.653

Google Scholar

[7] H. Kimura, K. Matsutani, S. Tsutsumi, et al: Catal. Lett. Vol. 99 (2005), p.119

Google Scholar

[8] Y. Yokota, Y. Sawamoto, H. Taniguchi, K. Okabe: Japanese Patent.(1986), 1,642,001.

Google Scholar

[9] Johan Runeberg, Alfons Baiker, Jacek Kijenski: Appl. Catal. Vol. 17 (1985), p.309

Google Scholar

[10] M. Imabeppu, K. Kiyoga, S. Okamura, et al: Cata Commun. Vol.10(2009), p.753

Google Scholar

[11] S. T. Balke, A. E. Hamielec: J Appl Polym Sci. Vol. 17(1973), p.905

Google Scholar

[12] P. J. Fydelor Swindon, David E. M. Taylor Hounslow: U.S. patent.(1983), 4, 377, 010

Google Scholar

[13] Xu Y. Z, Li W. H, Peng Q, Xu Z. H, et al: Spectro and Spec Analy. Vol.17(1997), p.55

Google Scholar