Modeling of Thermal Effect of Chemical Reactions in Heap Bioleaching of Chalcopyrite

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Abstract:

Heap bioleaching is regarded as an environmental-friendly technology to extract valuable metals, such as gold, silver, copper, etc., from low grade or waste ores. The chemical reactions accelerated by microorganisms are usually complex. Microbial activity is ascribed to the physiochemical factors such as temperature. Due to the variety of ore components, the thermal effect is difficult to elaborate. In this study, typical ores used for heap bioleaching of chalcopyrite are theoretically analyzed to explore the mechanism involving the thermal effect of chemical reactions. The thermal distribution is compared between different proportional combinations. The results show that biotite is the dominant contributor and should be verified carefully in the heap bioleaching of chalcopyrite.

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Advanced Materials Research (Volumes 455-456)

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1009-1012

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] T. V. Ojumu, J. Petersen, G. E. Searby, and G. S. Hansford, A review of rate equations proposed for microbial ferrous-iron oxidation with a view to application to heap bioleaching, Hydrometallurgy, vol. 83, pp.21-28, (2006).

DOI: 10.1016/j.hydromet.2006.03.033

Google Scholar

[2] A. K. Halinen, N. Rahunen, A. H. Kaksonen, and J. A. Puhakka, Heap bioleaching of a complex sulfide ore Part I: Effect of pH on metal extraction and microbial composition in pH controlled columns, Hydrometallurgy, vol. 98, pp.92-100, (2009).

DOI: 10.1016/j.hydromet.2009.04.005

Google Scholar

[3] A. K. Halinen, N. Rahunen, A. H. Kaksonen, and J. A. Puhakka, Heap bioleaching of a complex sulfide ore: Part II. Effect of temperature on base metal extraction and bacterial compositions, Hydrometallurgy, vol. 98, pp.101-107, (2009).

DOI: 10.1016/j.hydromet.2009.04.004

Google Scholar

[4] H. M. Lizama, Copper bioleaching behaviour in an aerated heap, International Journal of Mineral Processing, vol. 62, pp.257-269, (2001).

DOI: 10.1016/s0301-7516(00)00057-0

Google Scholar

[5] N. Pradhan, et al., Heap bioleaching of chalcopyrite: A review,. Minerals Engineering, vol. 21, pp.355-365, (2008).

DOI: 10.1016/j.mineng.2007.10.018

Google Scholar

[6] A. Rubio and F.J. Garcia-Frutos, Bioleaching of an extremely thermophilic culture for chalcopyritic materials,. Minerals Engineering, vol. 15, pp.689-694, (2002).

DOI: 10.1016/s0892-6875(02)00124-3

Google Scholar

[7] M. Qui, et al., A comparison of bioleaching of chalcopyrite using pure culture or mixed culture,. Minerals Engineering, vol. 18, pp.987-990, (2005).

DOI: 10.1016/j.mineng.2005.01.004

Google Scholar

[8] Y. Rodriguez, et al., New information on the chalcopyrite bioleaching mechanism at low and high temperature,. Hydrometallurgy, vol. 71, pp.47-56, (2003).

DOI: 10.1016/s0304-386x(03)00173-7

Google Scholar

[9] R.O. Sack and M.S. Ghiorso, Importance of considerations of mixing properties in establishing an internally consistent thermodynamic database: thermochemistry of minerals in the system Mg2SiO4-Fe2SiO4-SiO2,. Contributions to Mineralogy and Petrology, vol. 102, pp.41-68, (1989).

DOI: 10.1007/bf01160190

Google Scholar

[10] L.T. Elkins and T.L. Grove, Ternary feldspar experiments and thermodynamic models,. American Mineralogist, vol. 75, pp.544-559, (1990).

Google Scholar

[11] R.G. Berman, Internally-consistent thermodynamic data for minerals in the system Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2,. Journal of Petrology, vol. 29, pp.445-522, (1988).

DOI: 10.1093/petrology/29.2.445

Google Scholar

[12] M.S. Ghiorso, et al., Thermodynamics of the Amphiboles: Fe, Mg-cummingtonite solid solutions,. American Mineralogist, vol. 80, pp.502-519, (1995).

DOI: 10.2138/am-1995-5-611

Google Scholar