Preparation and Properties of Polycarboxylate Superplasticizer with Hydroxy Terminated Side Chains

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Abstract:

Maleic anhydride modified polycarboxylates superplasticizes (MPC) was synthesized from allylic poly (ethylene oxide ether) (APEG), maleic anhydride (MAH), sodium methylallyl sulfonate (SMAS) using ammonium persulfate (APS) as initiator. The optimal MPC with best fluidity was got at 90 °C when molar ratio of MAH, APEG, SAMA was 2.75∶1∶0.4 in the present of 4.5 mol% APS of all the monomer molars. MPC which possessed hydroxyl terminated side chains shows some difference in fluidity retarding related to the conventional superplasticizers possessed methoxy terminated side chains.

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Periodical:

Advanced Materials Research (Volumes 455-456)

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600-605

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January 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. Yamada, T. Takahashi, S. Hanehara, M. Matsuhisa, Effects of the chemical structure on the properties of polycarboxylate-type superplasticizer, Cem. Concr. Res. 30 (2) (2000) 197–207.

DOI: 10.1016/s0008-8846(99)00230-6

Google Scholar

[2] H. -Y. Cho, J. -M. Suh, and J. -M. Kim, Effects of poly{carboxylate-g-(ethylene glycol)methyl ether} on the physical properties of cement paste, Eurasian Chem. -Technol. J. 7 (1) (2005) 47-55.

DOI: 10.18321/ectj412

Google Scholar

[3] J. Plank, K. Pöllmann, and N. Zouaoui et al, Synthesis and performance of methacrylic ester based polycarboxylate superplasticizers possessing hydroxy terminated poly(ethylene glycol) side chains, Cem. Concr 38 (2008) 1210–1216.

DOI: 10.1016/j.cemconres.2008.01.007

Google Scholar

[4] J. Plank, and B. Sachsenhauser, Experimental determination of the effective anionic charge density ofpolycarboxylate superplasticizers in cement pore solution, Cem. Concr 39 (2009) 1-5.

DOI: 10.1016/j.cemconres.2008.09.001

Google Scholar

[5] K. Yoshioka, E. Tazawa, K. Kawai, and T. Enohata, Adsorption characteristics of waterreducerson cement component minerals, Cem. Concr. Res. 32 (2002) 1507–1513.

DOI: 10.1016/s0008-8846(02)00782-2

Google Scholar

[6] H. Uchikawa, S. Hanehara, and D. Sawaki, The role of steric repulsive force in the dispersion of cement particles in fresh paste prepared with organic admixture, Cem. Concr. Res. 27 (1997) 37–50.

DOI: 10.1016/s0008-8846(96)00207-4

Google Scholar

[7] YI-Shian Ye, Hung-Lung, and Huang, Kung-Chung Hsu, A water-soluble acrylate/sulfonate cooilymer.I. its synthesis and disersing ability on cement, Jounary of applied polymer science, 100 (2006) 2490–2496.

DOI: 10.1002/app.23606

Google Scholar