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Preparation and Properties of Polycarboxylate Superplasticizer with Hydroxy Terminated Side Chains
Abstract:
Maleic anhydride modified polycarboxylates superplasticizes (MPC) was synthesized from allylic poly (ethylene oxide ether) (APEG), maleic anhydride (MAH), sodium methylallyl sulfonate (SMAS) using ammonium persulfate (APS) as initiator. The optimal MPC with best fluidity was got at 90 °C when molar ratio of MAH, APEG, SAMA was 2.75∶1∶0.4 in the present of 4.5 mol% APS of all the monomer molars. MPC which possessed hydroxyl terminated side chains shows some difference in fluidity retarding related to the conventional superplasticizers possessed methoxy terminated side chains.
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600-605
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January 2012
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© 2012 Trans Tech Publications Ltd. All Rights Reserved
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