Electrochemical Properties of LiMnPO4 Cathode Material Prepared by Ball-Milling

Article Preview

Abstract:

The ball-milling LiMnPO4 powders for lithium-ion batteries were synthesized by high temperature solid-phase method. The effects of ball-milling on the microstructure and electrochemical performance of LiMnPO4 cathode material were investigated. The XRD patterns showed that the LiMnPO4 sample with ball milling 20h had single ordered olivine structure. The SEM images revealed that spherical particles distributed uniformly. The LiMnPO4 powders, of which the initial charge and discharge capacities at 0.05C rate were 133.9 and 66.4mAh•g-1 at 0.05C rate were prepared at 700°C for 20h with ball milling 20h.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

735-738

Citation:

Online since:

March 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc. 144 (1997) 1188.

Google Scholar

[2] B. Kang, G. Ceder, Nature 458 (2009) 190.

Google Scholar

[3] M. Konarova, I. Taniguchi, Powder Technol. 191 (2009) 111.

Google Scholar

[4] M. Konarova, I. Taniguchi, J. Power Sources 195 (2010) 3661.

Google Scholar

[5] A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc.144 (1997) 1188-1194.

Google Scholar

[6] A. Yamada, S.C. Chung, J. Electrochem. Soc. 148 (2001) 960-967.

Google Scholar

[7] C. Delacourt, L. Laffont, R. Bouchet, C. Wurm, J.B. Leriche, M. Morcrette, J.M. Tarascon, C. Masquelier, J. Electrochem. Soc. 152 (2005) 913-921.

DOI: 10.1149/1.1884787

Google Scholar

[8] M. Yonemura, A. Yamada, Y. Takei, N. Sonoyama, R. Kanno, J. Electrochem.Soc. 151 (2004) 1352-1356.

Google Scholar

[9] A.Yamada, S.C. Chung, K. Hinokuma, J. Electrochem. Soc. 148 (2001) 224-229.

Google Scholar

[10] P.P. Prosini, M. Carewska, S. Scaccia, P. Wisniewski, M. Pasquali, Electrochim.Acta 48 (2003) 4205-4211.

DOI: 10.1016/s0013-4686(03)00606-6

Google Scholar

[11] C.H. Mi, X.B. Zhao, G.S. Cao, J.P. Tu, J. Electrochem. Soc. 152 (2005)483-487.

Google Scholar

[12] S.T. Myung, S. Komaba, N. Hirosaki, H. Yashiro, N. Kumagai, Electrochim.Acta 49 (2004) 4213-4222.

DOI: 10.1016/j.electacta.2004.04.016

Google Scholar

[13] H. Huang, S.C. Yin, L.F. Nazar, Electrochem. Solid-State Lett. 4 (2001)170-172.

Google Scholar