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Downconversion for Solar Cells in Sr3Gd(PO4)3:Tb, Yb Phosphors

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Abstract:

An efficient near-infrared (NIR) quantum cutting (QC) Tb3+ and Yb3+ co-doped phosphor Sr3Gd(PO4)3 has been synthesized by conventional high temperature solid technique. Upon excitation of Tb3+ with a visible photon at 485 nm, two NIR photons could be emitted by Yb3+ through cooperative energy transfer (CTE) from Tb3+ to two Yb3+ ions. Excitation and emission spectra as well as fluorescence decay measurements have been carried out to examine the occurrence of cooperative energy transfer (CET ) from Tb3+ to Yb3+ ions. The result indicates Tb3+ and Yb3+ co-doped Sr3Gd(PO4)3 is potentially used as down-converter layer in silicon-based solar cell.

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Periodical:

Advanced Materials Research (Volume 502)

Pages:

136-139

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.502.136

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Online since:

April 2012

Authors:

Jia Yue Sun, Yi Ning Sun, Ji Cheng Zhu, Jun Hui Zeng, Hai Yan Du

Keywords:

Cooperation Energy Transition, Downconvertion, Quantum Cutting

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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