Preparation of Delithiated Cathode Materials of Li-Ion Battery by Chemical Extraction Employing Na2S2O8

Article Preview

Abstract:

A method of conventional chemical reaction to prepare delithiated cathode materials of Li-ion battery has been introduced. The cathode material of Li-ion battery was mixed with oxidizing agent Na2S2O8 in water, and the liquid was stirred continuously to make the chemical reaction proceed sufficiently, then the reaction product was filtered, finally the insoluble delithiated cathode material was obtained. A series of tests were conducted to verify the composition, crystal structure and electrochemical property of the delithiated cathode materials were all desirable. This method overcomes the shortcomings of battery charging preparation and chemical extraction preparation employing other oxidizing agents.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 512-515)

Pages:

969-975

Citation:

Online since:

May 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. Ermete: LiCoO2: Solid State Ionics Vol. 170 (2004), p.159

Google Scholar

[2] S. Choi, A. Manthiram: J. Electrochem. Soc. Vol. 149 (2002), p. A162

Google Scholar

[3] Y. C. Yao, Y. N. Dai, B. Yang:. Journal of Wuhan University of Technology-Mater. Sci. Ed. Vol. 22 (2007), p.307

Google Scholar

[4] G. G. Amatucci, J. M. Tarascon, L. C. Klein: J. Electrochem. Soc. Vol. 143 (1996), p.1114

Google Scholar

[5] J. N. Reimers, J. R. Dahn, U. Von: J. Electrochem. Soc. Vol. 140 (1993), p.2752

Google Scholar

[6] H. Gabrisch, R. Yazami, B. Fultz B: J. Power Sources Vol. 119-121 (2003), p.674

DOI: 10.1016/s0378-7753(03)00234-9

Google Scholar

[7] R. Gupta, A. Manthiram: J. Solid State Chemistry Vol. 121(1996), p.483

Google Scholar

[8] M. N. Obrovac, O. Mao, J. R. Dhan: Solid State Ionics Vol. 112 (1998), p.9

Google Scholar

[9] A. Ermete: Int. J. Inorg. Mater. Vol. 103 (2001), p.721

Google Scholar

[10] J. N. Reimers, J. R. Dahn: J. Electrochem. Soc. Vol. 139 (1992), p. (2091)

Google Scholar

[11] A. Van der ven, M. K. Aydinol, G. Ceder: Phys. Rev. B Vol. 58 (1998), p.58(6): 2975

Google Scholar

[12] A. Van der VEN, G. Ceder: Phys. Rev. B Vol. 59 (1999-II), p.742

Google Scholar

[13] J. P. Peres, F. Weill, C. Delmas: Solid State Ionics Vol.116 (1999), p.19

Google Scholar

[14] H. F. Wang, Y. I. Jang, B. Y. Huang: J. Electrochem. Soc. Vol. 146 (1999), p.473

Google Scholar

[15] Y. Shao-horn, S. Levasseur, F. Weill: J. Electrochem. Soc. Vol. 150 (2003), p. A366

Google Scholar