Thermal Decomposition Characteristics of Calcium Based Organic Compounds under Carbon Dioxide Enriched Atmosphere through Thermogravimetric Analysis

Abstract:

Thermal decomposition characteristics of two kinds of calcium based organic compounds-calcium propionate and the product of the modified calcium hydroxide by propionic acid-under O2/N2 atmosphere and O2/CO2 atmosphere are investigated through thermogravimetric analysis. Thermal events of CP and MCP are divided into three segments. The second and the third ones for the two compounds are similar. O2/CO2 atmosphere reduces mass loss rate peak of the second segment and postpone the third segment. O2 concentration of 10 % is inadequate for a fast and sufficient reaction. When O2 concentration is enriched to 20 %, the whole process is shifted towards lower temperature zone. Further heightening O2 concentration to 30 % or 40 %, the effect is not remarkable.

• Periodical: Advanced Materials Research (Volumes 516-517)
• Pages: 494-497
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.516-517.494
• Online since: May 2012
• Authors: Sheng Li Niu, Ying Jie Li, Kui Hua Han, Jian Li Zhao, Chun Mei Lu
• Keywords: Calcium Based Organic Compound, O₂/CO₂ Atmosphere, Thermogravimetric Analysis (TGA)

References

[1] S.L. Niu, K.H. Han and C.M. Lu: Process. Saf. Environ. Vol.89(2011), p.121.

[2] A.A. Patsias, W. Nimmo, B.M. Gibbs and P.T. Williams: Fuel. Vol.84(2005),p.1864.

[3] Y.J. Li, C.S. Zhao, H.C. Chen, C. Liang, L.B. Duan and W. Zhou: Fuel, Vol.88(2009), p.697.

[4] B.J.P. Buhre, L.K. Elliott, C.D. Sheng, R.P. Gupta and T.F. Wall: Prog. Energ. Combust. Vol.31(2005), p.283.

[5] D.L. Guerra, E.M. Silva and C. Airoldi: Process. Saf. Environ. Vol.88 (2010), p.53.

[6] S.L Niu, K.H Han, C.M Lu and R.Y. Sun: Appl. Energ. Vol.87(2010), p.2237.

[7] W. Nimmo, A.A. Patsias, W.J. Hall and P.T. Williams: Ind. Eng. Chem. Res. Vol.44(2005),p.4484.

[8] M.V. Kok: J. Therm. Anal. Calorim. Vol.97( 2009), p.397.