Fabrication of Dye Sensitized Solar Cell Based on TiO2 Nanoparticles and Chlorophyll from Pandan Leaf as Active Layer

Article Preview

Abstract:

Dye sensitized solar cell (DSSC) is a new class of low-cost solar cell, that belongs to third generation solar cells in thin film based. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, known as photoelectrochemical system. A lot of research has been conducted due to their interesting potential for low-cost, lightweight, disposable and having cell efficiency up to 10%. This paper reports the fabrication of dye sensitized solar cells using TiO2 nanoparticles and chlorophyll as active layer. TiO2 nanoparticles were prepared by sol-gel method while the chlorophyll was extracted from Pandanus amaryllifolius (Pandan leaf). TiO2 film was prepared on ITO coated glass using dip coating technique and then immersed overnight in the chlorophyll solution. An electrolyte solution composed of PC-LiClO4 was injected into the cell before sealed using glass that was coated with Pt as top electrode. An active area of 4.48 cm2 was fabricated by black masking the front side. The performance of the device was studied by observing the current-voltage characteristics of the device in dark at ambient temperature and under illumination of 100 mW/cm2 light. It was found that the device showed rectifier property in the dark and able to generate electrical current under light.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

405-409

Citation:

Online since:

July 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] S. Furukawa, H. Iino, T. Iwamoto, K. Kukita and S. Yamauch: Thin Solid Films, Vol. 518, Issue 2 (2009), pp.526-529.

DOI: 10.1016/j.tsf.2009.07.045

Google Scholar

[2] P.M. Sirimanne, M.K.I. Senevirathna, E.V.A. Premalal, P.K.D.D.P. Pitigala, V. Sivakumar and K. Tennakone: Journal of Photochemistry and Photobiology A: Chemistry, Volume 177, Issues 2-3 (2006), pp.324-327.

DOI: 10.1016/j.jphotochem.2005.07.003

Google Scholar

[3] S. Hao, J. Wu, Y. Huang and J. Lin: Solar Energy, Volume 80, Issue 2 (2006), pp.209-214.

Google Scholar

[4] G.R.A. Kumara, S. Kaneko, M. Okuya, B. Onwona-Agyeman, A. Konno and K. Tennakone: Solar Energy Materials and Solar Cells, Volume 90, Issue 9 (2006), pp.1220-1226.

DOI: 10.1016/j.solmat.2005.07.007

Google Scholar

[5] C. G. Garcia, A. S. Polo and N. Y. Murakami Iha: Journal of Photochemistry and Photobiology A: Chemistry, Volume 160, Issues 12 (2003), pp.87-91.

Google Scholar

[6] A.O.T. Patrocínio, S.K. Mizoguchi, L.G. Paterno, C.G. Garcia and N.Y. Murakami Iha: Synthetic Metals, Volume 159, Issues 21-22 (2009), pp.2342-2344.

DOI: 10.1016/j.synthmet.2009.08.027

Google Scholar

[7] A. Pfarrherr, K. Teuchner, D. Leupold and P. Hoffmann: Journal of Photochemistry and Photobiology B: Biology, Volume 9, Issue 1 (1991), pp.35-41.

DOI: 10.1016/1011-1344(91)80002-y

Google Scholar

[8] W. M. Campbell, A. K. Burrell, D. L. Officer and K. W. Jolley: Coordination Chemistry Reviews, Volume 248, Issues 13-14 (2004), pp.1363-1379.

DOI: 10.1016/j.ccr.2004.01.007

Google Scholar

[9] M. Grätzel: Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Volume 4, Issue 2 (2003)., pp.145-15331.

Google Scholar

[10] M. Y. A. Rahman, M. M. Salleh, I. A. Talib and M. Yahaya: Journal of Power Sources, Volume 133, Issue 2 (2004), pp.293-297.

Google Scholar

[11] K. Hara, T. Nishikawa, M. Kurashige, H. Kawauchi, T. Kashima, K. Sayama, K. Aika, H. Arakawa: Solar Energy Materials and Solar Cells, Volume 85, Issue 1 (2005), pp.21-30.

Google Scholar

[12] S. S. Kim, Y. C. Nah, Y. Y. Noh, J. Jo and D. Y. Kim: Electrochimica Acta, Volume 51, Issue 18 (2006), pp.3814-3819.

DOI: 10.1016/j.electacta.2005.10.047

Google Scholar