Determination of the Curing Techniques of Octaepoxysilsesquioxane with a Diamine

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Abstract:

Octaepoxysilsesquioxane (POSS-Ep), a kind of functional polyhedral oligomeric silsesquioxane (POSS) was cured with 4,4'-diaminodiphenylsulfone diamine (DDS) in this study. Possessing epoxy groups, it can be cured thermally with certain curing agents including amines. Differential scanning calorimetry (DSC) was used to determine the curing techniques of the POSS-Ep/DDS resin system in this study. The appropriate curing technique for this resin is set as: 130°C/2h+ 160°C/2h+200°C/2h.

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157-160

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July 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] R.H. Banley, M. Itoh, A. Sakakibara and T. Suzuki: Chem. Rev. 95, (1995), p.1409.

Google Scholar

[2] J.D. Lichtenhan, Y. Otonari and M.J. Carr: Macromolecules. 28, (1995), p.4355.

Google Scholar

[3] T.S. Haddad and J.D. Lichtenhan: Macromolecules. 29, (1996), p.234.

Google Scholar

[4] F.J. Feher, J.J. Schwab, D.M. Tellers and A. Burstein: Main. Group. Chem. 2, (1998), p.123.

Google Scholar

[5] J. Choi, J. Harcup and A.F. Yee: J. Am. Chem. Soc. 123, (2001), p.11420.

Google Scholar

[6] M.J. Abad, L. Barral, D. Fasce and R.J. Williams: Macromolecules. 36, (2003), p.3128.

Google Scholar

[7] G.M. Kim, H. Qin, X. Fang, F.C. Sun and P.T. Mather: J. Polym. Sci., Polym. Phys. 41, (2003), p.3299.

Google Scholar

[8] J. Choi, A.F. Yee and R.M. Laine: Macromolecules. 36, (2003), p.5666.

Google Scholar

[9] C. Zhang, F. Babonneau, C. Bonhomme, R.M. Laine, C.L. Solesand and H.A. Hristov: J. Am. Chem. Soc. 120, (1998), p.8380.

Google Scholar

[10] J.D. Lichtenhan, Y.A. Otonari and M.J. Carr: Macromolecules. 28, (1995), p.8435.

Google Scholar

[11] D. Neumann, M. Fisher, L. Tran and J.G. Matisons: J. Am. Chem. Soc. 124, (2002), p.13998.

Google Scholar

[12] K.M. Kim, D.K. Keum and Y. Chujo: Macromolecules. 36, (2003), p.867.

Google Scholar

[13] Z.H. Liu: Introduction Of Thermal Analysis (Beijing: Chemical Industry Press, 1990).

Google Scholar

[14] H.E. Kissinger: Anal. Chem., 29, (1957), p.1702.

Google Scholar

[15] P. Chen and D.Z. Wang: Epoxy Resin And The Application (Beijing: Chemical Industry Press, 2004).

Google Scholar