Synthesis and Properties of Cellulose Diacetate Graft Poly(p-dioxanone) Copolymers via the Couple-Grafting Copolymerization

Abstract:

A new biodegradable copolymer of cellulose diacetate and poly(p-dioxanone) (PPDO) was prepared through a couple-grafting procedure. PPDO was functionalized with the isocyanate group, and then PPDO terminated with the isocyanate group was enabled to react with the hydroxyl groups of cellulose diacetate. The length of PPDO graft chains can be controlled easily by using the prepolymers of PPDO with different molecular weights. The resulting products were thoroughly characterized with FT-IR, ¹H-NMR. The mechanical properties of the copolymers were affected greatly by the length of PPDO segment.

• Periodical: Advanced Materials Research (Volume 549)
• Pages: 3-7
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.549.3
• Online since: July 2012
• Authors: Jiang Zhu, Xiu Li Wang
• Keywords: Cellulose Diacetate, Graft Copolymer, Mechanical Property, P-Dioxanone

References

[1] I. C. Eromosele, T. J. Hamgadu: J. Appl. Polym. Sci. Vol. 50 (1993), p.645.

[2] C. J. Edgar, C. M. Buchanan, J. S. Debenham, P. A. Rundquist, B. D. Seiler, M. C. Shelton： Prog. Polym. Sci. Vol. 26 (2001), p.1605.

[3] C. M. Buchanan, R. M. Gardner, R. J. Komarek: J. Appl. Polm. Sci. Vol. 47 (1993), p.1709.

[4] R. J. Komarek, R. M. Gardner, C. M. Buchanan, S. C. Gedon: J. Appl. Polm. Sci. Vol. 50 (1993), p.1739.

[5] k. Sakai, T. Yamauch, F. Nakatsu, T. Ohe: Biosci. Biotech. Biochem. Vol. 60 (1996), p.1617.

[6] M. Yoshioka, N. Hagiwara, N. Shiraishi: Cellulose Vol. 6 (1999), p.193.

[7] Y. Nishio, J. F. Kenedy, G. O. Phillips, P. A. Williams, in: Wood Processing and Utilization; Ellis Horwood: New York, 1989; p.251.

[8] Y. Teramoto, M. Yoshioka, N. Shiraishi, Y. Nishio: J. Appl. Polym. Sci. Vol. 84 (2002), p.2621.

[9] Y. Miyashita, T. Suzuki, Y. Nishioka: Cellulose Vol. 9 (2002), p.215.

[10] Y. Nishioka, K. Matsuda, Y. Miyashita, N. Kimura, H. Suzuki: Cellulose Vol. 4 (1997), p.131.

[11] M. Yoshika, N. Hagiwara, N. Shiraishi: Cellulose Vol. 6 (1999), p.193.

[12] M. Yoshika, K. Okajima, T. Miyazaki, N. Shiraishi: J. Wood Sci. Vol. 46 (2000), p.22.

[13] H. Hatakeyana, T. Yoshida, T. Hatakeyama: J. Therm. Anal. Calorim. Vol. 59 (2000), p.157.

[14] Y. Teramoto, M. Yoshika, N. Shiraishi, Y. Nishio: J. Appl. Polym. Sci. Vol. 84 (2002), p.2621.

[17] Y. Teramoto, Y. Nishio: Polymer Vol. 44 (2003), p.2701.

[18] K. K. Yang, X. L. Wang, Y. Z. Wang: J. Macromol. Sci. Polym. Rev. Vol. C42 (2002), p.373.

[19] S. C. Chen, X. L. Wang, Y. Z. Wang, K. K. Yang, Z. X. Zhou, G. Wu: J. Biomed. Mater. Res. Part A Vol. 82A (2007), p.453.

[20] G. Y. Liu, Y. L. Zhai, X. L. Wang, W. T. Wang, Y. B. Pan, X. T. Dong, Y. Z. Wang: Carbohydr. Polym. Vol. 74 (2008), p.862.

[21] R. He,; X. L. Wang, Y. Z. Wang, K. K. Yang, J. B. Zeng, S. D. Ding: Carbohydr. Polym. Vol. (2006), p.28 Table 1 Effect of the intrinsic viscosities of the PPDOs on the coupling reaction CDA/PPDO (g/g) Reaction Time (h) Reaction Temperature (℃).