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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 549Chemical Fixation of Carbon Dioxide Catalyzed by...

Chemical Fixation of Carbon Dioxide Catalyzed by Bimetallic Aluminum(Salen) Complex

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Abstract:

Bimetallic aluminum(salen) complexes were prepared and used as catalyst for the synthesis of DPC from CO₂ and phenol in the presence of carbon tetrachloride. The bimetallic complex derived from 3,5-ditert salicylaldehyde and 1,2-cyclohexanediamine revealed more excellent activity than that obtained in the presence of other complexes and the simple Lewis acid ZnCl₂. The influence of the amount of complex and the reaction conditions including the pressure of CO₂ and the reaction temperature was also investigated.

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Chemical Engineering and Material Properties II

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Periodical:

Advanced Materials Research (Volume 549)

Pages:

406-410

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.549.406

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Online since:

July 2012

Authors:

Zhen Xiao Duan, Tao Fang, Min Wang, Guo Zhi Fan

Keywords:

Bimetallic Aluminum(salen) Complex, Carbon Dioxide, Diphenyl Carbonate, Phenol

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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