Alternating Copolymerization of Carbon Dioxide with Cyclohexene Oxide Catalyzed by a Novel Catalyst

Abstract:

Article Preview

A novel catalyst for the copolymerization of CO2 and cyclohexene oxide(CHO) was prepared by using BTE and ZnCl2. The zinc complex showed catalytic activity for the copolymerization. The obtained copolymer was characterized by IR and NMR. Effect of reaction time on copolymerization was investigated.

Info:

Periodical:

Edited by:

Bin Li

Pages:

445-448

Citation:

L. D. Fan et al., "Alternating Copolymerization of Carbon Dioxide with Cyclohexene Oxide Catalyzed by a Novel Catalyst", Advanced Materials Research, Vol. 549, pp. 445-448, 2012

Online since:

July 2012

Export:

Price:

$41.00

[1] S. Inoue, H. Koinuma and T. Tsuruta, J. Polym. Sci., Part B: Polym. Lett. Vol. 7(1969), p.287.

[2] C. M. Byrne, S. D. Allen, E. B. Lobkovsky and G. W. Coates, J. Am. Chem. Soc. Vol. 126(2004), p.11404.

[3] K. Nakano, T. Kamada and K. Nozaki, Angew. Chem. Int. Ed. Vol. 45(2006), p.7274.

[4] E. K. Noh, S. J. Na, S. S, S. W. Kim and Y. L. Bun, J. Am. Chem. Soc. Vol. 129(2007), p.8082.

[5] S. S, J. K. Min, J. E. Seong, S. J. Na and B. Y. Lee, Angew. Chem. Int. Ed. Vol. 47(2008), p.7306.

[6] B. Y. Liu, X. Zhao, H. F. Guo, Y. H. Gao, M. Yang and X. H. Wang, Polymer. Vol. 50(2009), p.5071.

[7] X. B. Lu, L. Shi, Y. M. Wang, R. Zhang, Y. J. Zhang, X. J. Peng, Z. C. Zhang and B. Li, J. Am. Chem. Soc. Vol. 128(2006), p.1664.