Dyeing Acceleration Theory of Molecule Companion on Silk with Reactive Dyes

Abstract:

In this paper, a novel high efficient dyeing acceleration theory of molecule companion(DATMC) on silk with reactive dyes was invented and studied. Organic cations were used as accelerants to company reactive dyes to dye on silk, and the dyed silk was washed with anionic surfactant. The results showed that the dye-uptake rates were very high, nearly 100%. But if the carbon atom number of hydrophobic hydrocarbon chain of organic cation was equal to or more than 12, the organic cation would affect the fixation reaction of reactive dye on silk. On the contrary, if it was equal to or less than 8, the fixation reaction would be accelerated. The fixation rates were 98.10% and 98.48% with octyl trimethyl ammonium bromide(OTAB) and hexyl butyl dimethyl ammonium bromide(HBDAB) as accelerants, respectively. The fastnesses of dyed silk were 4-5, and the silk could be dyed uniformly if the accelerant was added in several times.

• Periodical: Advanced Materials Research (Volume 549)
• Pages: 70-73
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.549.70
• Online since: July 2012
• Authors: Guang Xian Zhang, Ling Zhong, Feng Xiu Zhang, Xu Ting Xue, Ming Lu, Hui Zheng, Da Yang Wu
• Keywords: Accelerant, DATMC, Organic Cation, Reactive Dyes

References

[1] K. Sawadaa, M. Uedab. Dyeing of protein fiber in a reverse micellar system[J]. Dyes and Pigments, 2003, 5(8), 99-203.

[2] M. van der Kraan, M.V. Fernandez Cid , G.F. Woerlee ,W.J.T. Veugelers , C.J. Peters , G.J. Witkamp. Equilibrium distribution of water in the two-phase system supercritical carbon dioxide–textile[J]. J. of Supercritical Fluids, 2007, 40: 336–343.

DOI: 10.1016/j.supflu.2006.07.018

[3] S.M. Burkinshaw, M. Paraskevas. The dyeing of silk: Part 4 heterobifunctional dyes[J]. Dyes and Pigments, 2011, 88（3）: 396-402.

DOI: 10.1016/j.dyepig.2010.08.018

[4] S.M. Burkinshaw, M. Paraskevase. Deing of silk Part 1: Low temperature application of solubilised sulphur dyes using sodium thioglycolate[J]. Dyes and Pigments, 2010, 87, （3）: 225-233.

DOI: 10.1016/j.dyepig.2010.03.031

[5] S. Phattanarudee, K. Chakvattanathamand S. Kiatkamjornwong. Pretreatment of silk fabric surface with amino compounds for ink jet printing[J]. Progress in Organic Coatings, 2009, 64（4）, Pages 405-418.

DOI: 10.1016/j.porgcoat.2008.08.002

[6] Kongliang Xie, Yanna Liu , Xiaochun L. Synthesis and properties of the novel surface-active dyes containing fluorocarbon groups: Part 2. Dyeing diffusion kinetics of the novel surface-active dyes on silk fabric[J]. Materials Chemistry and Physics, 2007, 105( 2-3), 15 : 204-207.

DOI: 10.1016/j.matchemphys.2007.04.043

[7] Bingtao Tang, Shufen Zhang, Jinzong Yang, Feng Liu. Synthesis of a novel water-soluble crosslinking polymeric dye with good dyeing properties[J]. Dyes and Pigments, 2006, 68: 69~73.

DOI: 10.1016/j.dyepig.2004.11.005

[8] Ling Zhong, Guangxian Zhang, Fengxiu Zhang, Xuting Xue. Adsorption Kinetic Study of Reactive Dyes on Silk with Octyl Trimethyl Ammonium Bromide as Accelerant[J], Advanced Materials Research Vol. 331 (2011) pp.291-297.

DOI: 10.4028/www.scientific.net/amr.331.291