Synthesis of Ethyl Acetate Using Packing Solid Super Acid Catalyst of SO42-/Al2O3 by Catalytic Distillation

Guo Fu Sun; Jing Li Xu; Hong Yan Si

doi:10.4028/www.scientific.net/AMR.550-553.292

Paper Titles

Promoting Effect of Cobalt Addition on Higher Alcohols Synthesis over Copper-Based Catalysts
p.270

Nano-TiO₂ Photocatalytic Degradation N-Amyl Alcohol Research
p.276

Catalytic Effects of Super Acid SO₄^2-/γ-Al₂O₃ to PET Depolymerization under Microwave Irradiation
p.280

Research Progress of Unsupported Nano Catalyst
p.284

Synthesis of Ethyl Acetate Using Packing Solid Super Acid Catalyst of SO₄^2-/Al₂O₃ by Catalytic Distillation
p.292

Cationic Polymerization of β-Pinene Using Keggin Phosphotungstates as Catalysts
p.296

Ethylbenzene Dehydrogenation with CO₂ over V₂O₅-Fe₂O₃/Al₂O₃-TiO₂ Catalyst
p.301

Thermally Stable Metal(Cu, Fe)-Substituted Mesoporous Aluminophosphates: Synthesis and Application as Oxidation Catalysts
p.306

Studies on the Catalytic Performance of the Nieuwland Catalyst and Anhydrous Catalyst in the Dimerization of Acetylene to Monovinylacetylene
p.312

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Synthesis of Ethyl Acetate Using Packing Solid...

Synthesis of Ethyl Acetate Using Packing Solid Super Acid Catalyst of SO₄^2-/Al₂O₃ by Catalytic Distillation

Abstract:

Ethyl acetate was synthesized by catalytic distillation using packing solid super acid catalyst of SO₄^2-/Al₂O₃ made by oneself. The effects of process parameters such as the ratio between acetic acid and ethanol, the feed flow rate of ethanol and reflux ratio on catalytic distillation were observed. The best operation parameters were determined. It was beneficial for synthesis of ethyl acetate when n(acetic acid)/n(ethanol) was 1/3, the feed flow rate of ethanol was 3mol/l and reflux ratio was 2.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

292-295

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.550-553.292

Citation:

Cite this paper

Online since:

July 2012

Authors:

Guo Fu Sun, Jing Li Xu, Hong Yan Si

Keywords:

Catalytic Distillation (CD), Ethyl Acetate, Packing Solid Super Acid, SO₄^2-/Al₂O₃

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Jingli Xu, Guofu Sun, Research advances of solid acid catalyst in esterification reaction, J. of Jilin Institute of Chemical Technology, 18(2001) 87-90

Google Scholar

[2] Fang Li and Chunmei Ding, Esterfication over Nano Solid Superacid SO42-/ZrO2-Sm2O3-SiO2, Advanced Materials Research, 194-196(2011) 2503-2506

Google Scholar

[3] Shaohua Fan, Wenbao Zhang etc., Application of solid super-acid in esterification reaction, Chemical Engineering,34(2006)71-74

Google Scholar

[4] LI Jiagui WEI Qingmin etc., Synthesis of cyclohexanone 1,2-propanediolketal catalyzed by nanosolid superacid SO2-4/Fe2O3, Industrial Catalysts, 18(2010) 48-51

Google Scholar

[5] Park YM, Chung SH etc., Tungsten oxide zirconia as solid superacid catalyst for esterification of waste acid oil (dark oil), Bioresour Technol. 101(2010)6589-6593

DOI: 10.1016/j.biortech.2010.03.109

Google Scholar

[6] Guanzhong Lu, Catalytic properties of SO42−Ti-M-O superacids in esterification, Applied Catalysis A:General, 133(1995)11-18

DOI: 10.1016/0926-860x(95)00170-0

Google Scholar

[7] Yan Li, Xiao-Dong Zhang etc., Fatty acid methyl ester synthesis catalyzed by solid superacid catalyst SO42-/ZrO2-TiO2/ La3+ , Applied Energy, 87(2010) 156-159

DOI: 10.1016/j.apenergy.2009.06.030

Google Scholar

[8] Pingan Liao, Ping Lan etc., Synthesis of ethyl acetate using catalytic reaction distillation, Modern Chemical Industry, 9(1997) 25-27

Google Scholar

[9] Xien Xu, Shaoguang Song etc., Synthesis of Propylene Glycol Monoethyl Ether by Catalytic Distillation, Petroleum Chemical Journal, 26(1997) 209-212

Google Scholar