Ni/Y- Zeolite Catalysts for Carbon Dioxide Reforming of Methane

A.H. Fakeeha; A.S. Al–Fatesh; A.E. Abasaeed

doi:10.4028/www.scientific.net/AMR.550-553.325

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Ni/Y- Zeolite Catalysts for Carbon Dioxide...

Ni/Y- Zeolite Catalysts for Carbon Dioxide Reforming of Methane

Abstract:

Carbon deposits play a crucial role in the performance of catalysts, in terms of controlling both reaction selectivity and activity, this is most often manifest through catalyst deactivation. Understanding the structure and electronic properties of the carbon deposits formed on the surface of a catalyst is therefore an importance key. In this study the catalytic performance of Ni based on Y-Zeolite (CBV300) prepared by incipient wetness impregnation. The prepared catalyst was tested in a micro tubular reactor using temperature ranges of 500, 600 and 700 °C at atmospheric pressure, using a total flow rate of 36 ml/min consisting of 2 ml/min of N₂, 17 ml/min of CO₂ and 17 ml/min of CH₄. The calcination was carried out in the range of 500–900 °C. The catalyst is activated inside the reactor using hydrogen gas.The conversion of CH₄ observed over 5wt%Ni/ Y-Zeolite at 700 °C were 59.6%. The supported Ni catalysts were characterized by BET and TG/DTA techniques.

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Advanced Materials Research (Volumes 550-553)

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325-328

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https://doi.org/10.4028/www.scientific.net/AMR.550-553.325

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July 2012

Authors:

A.H. Fakeeha, A.S. Al–Fatesh, A.E. Abasaeed

Keywords:

CH₄, CO₂, Nickel Catalysts, Y Zeolite

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References

[1] V. Choudhary, V.R. Choudhary, Ang. Chem. Int. Ed. 47, (2008) 1828-147

Google Scholar

[2] P. Frontera • A. Aloise • A. Macario • F. Crea P. L. Antonucci • G. Giordano • J. B. Nagy, Res Chem Intermed (2011) 37:267–279

DOI: 10.1007/s11164-011-0249-3

Google Scholar

[3] B. Pavelec, S. Damyanova, K. Arishtirova, J. L. Fierro, L. Petrov, Appl. Catal. 30 (2007) 188-201.

Google Scholar

[4] A. N. Pinheiro, A. Valentini, J.M. Sasaki, A. C. Oliveira, Zeolites and Related Materials (2008) 205-208

Google Scholar

[5] Chang, J.-S., Park, S.E., and Chon, H., Appl. Catal., A,1996, vol. 145, 111-124.

Google Scholar

[6] Crisafulli C, Scire` S, Minio` S, Solarino L (2002) Appl Catal A Gen 225:1-11

Google Scholar

[7] A. Kaengsilalai, A. Luengnaruemitchai, S. Jitkarnka, S. Wongkasemjit, J. Power Sources 165 (2007) 347-352.

DOI: 10.1016/j.jpowsour.2006.12.005

Google Scholar

[8] K. Wang, X. Li, S. Ji, S. Sun, D. Ding, C. Li, Stud. Surf. Sci. Catal. 167 (2007) 367-372.

Google Scholar

[9] B. Pavelec, S. Damyanova, K. Arishtirova, J.L. Fierro, L. Petrov, Appl. Catal. A: Gen. 30 (2007) 188-201.

Google Scholar

[10] B. Bonelli, L. Forni, A. Aloise, J.B. Nagy, G. Fornasari, E. Garrone, A. Gedeon, G.Giordano, F. Trifiro, Microporous Mesoporous Mater. 101 (2007) 153-160.

DOI: 10.1016/j.micromeso.2006.11.006

Google Scholar

[11] J.A. Montoya, E. Romero-Pascual, C. Gimon, P. Del Angel, A. Monzon, Catal. Today 63 (2000) 71–85.

Google Scholar

[12] D. Halliche, O. Cherifi, Y.B. Taarit, A. Auroux, Kinet. Catal. 49 (2008).667-672.

DOI: 10.1134/s002315840805011x

Google Scholar

[13] A.S. Al–Fatish, A.A. Ibrahim, A.H. Fakeeha, M.A. Soliman, M.R.H. Siddiqui , A.E. Abasaeed, Appl. Catal., A: Gen. 364 (2009) 150-155.

DOI: 10.1016/j.apcata.2009.05.043

Google Scholar

[14] A.S. Al–Fatesh, and A. H. Fakeeha, Advanced Materials Research (2011) 233-235.

Google Scholar