Preparation and Analysis of Homo-Polymer and Copolymer from Tetra-Coordinate Silicate

Jian Hua Song; San Jun Fan

doi:10.4028/www.scientific.net/AMR.550-553.752

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Preparation and Analysis of Homo-Polymer and...

Preparation and Analysis of Homo-Polymer and Copolymer from Tetra-Coordinate Silicate

Abstract:

Highly reactive penta-coordinate organic silicon was prepared by the reaction of silica with ethylene glycol and potassium hydroxide, which reacted with 4-vinylbenzyl chloride to synthesize a new 4-vinyl benzyl tetra-coordinate silicate (VBTCS), and the new monomer was homo-polymerized and copolymerized with styrene and methyl acrylate via free radical polymerization, respectively. Tetra-coordinate silicon monomer, homo-polymer, and copolymers were characterized by IR, EA, TG, DSC, GPC etc.

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Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

752-756

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.550-553.752

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Online since:

July 2012

Authors:

Jian Hua Song, San Jun Fan

Keywords:

Copolymerized, Free Radical Polymerization, Homo-Polymerized, Penta-Coordinate Silicon, Tetra-Coordinate Silicon, VBTCS

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