Enzymatic and Chemical Synthesis and Characterization of Poly-6-O-(10-undecylenoyl) D-Glucose

Chao Wei; Yin Zhen Wang; Wei Yan; Ping Jia Yao; Yuan An Wei

doi:10.4028/www.scientific.net/AMR.550-553.787

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 550-553Enzymatic and Chemical Synthesis and...

Enzymatic and Chemical Synthesis and Characterization of Poly-6-O-(10-undecylenoyl) D-Glucose

Abstract:

Immobilized lipase Novozym-435 catalyzed regioselective synthesis of glucose and undecylenic acid(UA) to produce glucose mono-ester in Organic solvents was investigated. Reactionconditions were tested in order to produce the mono-ester more rapidly and in higher yield, the optimal conditions were obtained as: temperature at 50°C,mole ratio of glucose toUA of 1:2,concentration of molecular sieves and enzyme used as 0.56mg/mL and 10mg/mL respectively . After the reaction, product was purified, and characterized by MS and 13C NMR spectroscopy, and determined as 6-O-(10-undercylenoyl)-D-glucose, The product was used as the starting material, K2S2O8 as a chemical initiator, to polymerize and form the sugar-containing polymer, which could be used for medicine release agent and other application of biological materials.

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Periodical:

Advanced Materials Research (Volumes 550-553)

Pages:

787-791

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.550-553.787

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Online since:

July 2012

Authors:

Chao Wei, Yin Zhen Wang, Wei Yan, Ping Jia Yao, Yuan An Wei

Keywords:

6-O-(10-Undecylenoyl) D-Glucose, Lipase, Sugar Esters, Sugar-Containing Polymer

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References

[1] Z. G. Chen，M. H. Zong，W. Y. Lou: Chinese journal of molecular catalysis(In Chinese)Vol.21 (2007), p.90

Google Scholar

[2] M. V. Flores, K. Naraghi, J. M. Engasser and P. J. Halling: Biotechnology and Bioengineering Vol. 78 (2002), p.814

Google Scholar

[3] J. F. Kennedy, H. Kumar, P. S. Panesar, S. S. Marwaha, R. Goyal, A. Parmar and S. Kaur: Journal of Chemical Technology & Biotechnology Vol. 81(2006), p.866

Google Scholar

[4] Y. Z. He，P. J. Yao，Y. A.Wei: Polymer materials science & engineering(In Chinese) No.2 (2005)，p.61

Google Scholar

[5] B. Nigel, I. Jim, R. Lawrence et al : Antiviral Research, Vol.40 (1999), p.139

Google Scholar

[6] Q. B. Liu, H. Michiel, A. Janssen, F. V. Rantwijk and R. A. Sheldon: Green Chemistry(In Chinese), Vol. 7, (2005), p.39

Google Scholar

[7] Y. A. Wei, Y. Zhang and P. J. Yao: Journal of Guangxi University: Nat Sci Ed(In Chinese), Vol. 34(2009), p.484

Google Scholar

[8] F. Ganske and U. T. Bornscheuerv: Journal of Molecular Catalysis B: Enzymatic, Vol. 36, (2005), p.40

Google Scholar

[9] S. Riva, J. Chopineau, A. P. G. Kieboom and A. M. Klibanov: Journal of the American Chemical Society, Vol. 110(1988), p.584

Google Scholar

[10] R.Takao, K.Masaru, S.Hiromi et al: Biotechnology Lett Vol.161(2003), p.161

Google Scholar

[11] T.Yutaka, K.Masaru, R.Takao, et al : Bioorg. Med. Chem. Lett Vol.17(2007), p.3105

Google Scholar