Synthesis and Characterization of Novel Thermal Stability Poly (ester-imide-ether) with Excellent Lower Temperature Elastic Recovery

Abstract:

A new poly(ester-imide-ether) (PEIE) was prepared by melt polymerization from 1,4-butanediol(BD), polytetrahydrofuran diol (PTMG) and a novel imide dicarboxylic acid monomer which was synthesized from 3,3',4,4'-biphenyltetracarboxylic di-anhydride(BPDA) and glycine acid(GLY). The structure, thermal behaviour and elastic recovery of polymer were characterized by FT-IR. thermogravimetric analysis (TGA), differential scanning calorimetry thermograms (DSC) and laboratory stretching machine. The results showed this polymer has excellent thermal stability, 5 % weight loss temperature was at 354°C. Meanwhile, the DSC curve showed that glass-transition temperature and crystallization temperature of the polymer were at -30 °C and 160 °C, respectively. The excellent elastic recovery was still displayed at low temperature.

• Periodical: Advanced Materials Research (Volumes 554-556)
• Pages: 258-262
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.554-556.258
• Online since: July 2012
• Authors: Jiao Jiao Shang*, Jian Wu Lan, Shao Jian Lin, Si Chen, Ya Ni Li
• Keywords: Elastic Recovery, Melt Polymerization, Poly(ester-imide-ether), Thermo Plastic Elastomer

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