Synthesis, Characterization and Conductivity Study of Schiff Base Ligands Derived from Isatin

Muneera Fatin Manan; Karimah Kassim; Mohd Abdul Fatah Abdul Manan

doi:10.4028/www.scientific.net/AMR.554-556.517

Paper Titles

Adsorption Removal of Methyl Orange from Aqueous Solution by Mesoporous Al₂O₃
p.498

The Effect of Chromium on the Optical Properties and Photoactivity of Nano-Particulate Rutile
p.502

The Study on TiAl Alloy Powders with Different Density by Low Temperature Diffusion Synthesis
p.507

Separation Copper Ions from Aqueous Solution by Emulsion Liquid Membrane Using Novel PAMAMG4-1,2-Octenoxid Dendrimer as Carrier
p.511

Synthesis, Characterization and Conductivity Study of Schiff Base Ligands Derived from Isatin
p.517

Preparation of Composite Particles Containing Nano-CuO and Micron Flake Graphite
p.522

Effect of Carbon Source Content on the Carbothermal Synthesis of AlN Powders Using a Combustion Synthesis Precursor
p.526

Comparison between Conventional and Microwave-Assisted Synthesis of Cu-Containing Layered Double Hydroxides
p.532

Synthesis, Structure and Thermal Analysis of Zn(II)-Bi(III) Hetrometallic Complex with Ethylenediaminetetraacetate
p.536

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 554-556Synthesis, Characterization and Conductivity Study...

Synthesis, Characterization and Conductivity Study of Schiff Base Ligands Derived from Isatin

Abstract:

In this study, Schiff base ligands of (E)-3-(2-aminophenylimino)indolin-2-one, (L1); (E)-3-(2-amino-5-nitrophenylimino)indolin-2-one, (L2); and (E)-3-(2-amino-5-chlorophenylimino) indolin-2-one, (L3) were synthesized via condensation reaction of isatin with o-phenylenediamine, 4-nitro-o-phenylenediamine and 4-chloro-o-phenylenediamine respectively. All the synthesized compounds were characterized by various of physicochemical techniques such as melting point, elemental analysis, infrared spectroscopy, and ¹H nuclear magnetic spectroscopy. Conductivity studies of these ligands were investigated by impedance analyzer which the samples were prepared in the form of tablets. The electrical conductivities of the prepared compounds were measured by applying alternating current (ac) voltage. The conductivity values were calculated and result obtained shows that L2 has the highest conductivity value, followed by L3 and L1.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 554-556)

Pages:

517-521

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.554-556.517

Citation:

Cite this paper

Online since:

July 2012

Authors:

Muneera Fatin Manan, Karimah Kassim, Mohd Abdul Fatah Abdul Manan

Keywords:

Conductivity Study, Isatin, Schiff-Base

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] Sarkar S., Dey K. (2005) Synthesis and spectroscopic characterization of some transition metal complexes of a new hexadentate N2S2O2 Schiff base ligand. Spectrochimica Acta Part A 62 (2005) 383-393

DOI: 10.1016/j.saa.2005.01.005

Google Scholar

[2] Keypour H., Shayesteh M., Sharifi-Rad A., Salehzadeh S., Khavasi H., Valencia L. (2008) Synthesis and characterization of copper(II) and cobalt (II) complexes with two new potentially hexadentate Schiff base ligands. X-ray crystal structure determination of one copper(II) complex. Journal of Organomettalic Chemistry 693 (2008) 3179-3187

DOI: 10.1016/j.jorganchem.2008.07.012

Google Scholar

[3] Parekh J, Inamdhar P., Nair R., BalujaS. and Chanda S, (2005). Synthesis and antibacterial activity of some Schiff bases derived from 4-aminobenzoicacid, J.Serb Chem. Soc. 70 (10), 1155-1161.

DOI: 10.2298/jsc0510155p

Google Scholar

[4] Niume K., Kurosawa S., Toda F., Hasegawa M., Iwakura Y. (1982) The condensation of isatin with o-phenylenediamine. Bull. Chem. Soc. Jpn, 55, 2293-2294

DOI: 10.1246/bcsj.55.2293

Google Scholar

[5] Pavia, Lampman, Kriz and Vyvyan. (2007). Introduction to spectroscopy (fourth edition). Brooks/Cole CENGAGE Learning

Google Scholar

[6] Sarkar S., Biswas S., Liao M.S., Kar T., Aydogdu Y., Dagdelen F., Mostafa G., Chattopadhyay A.P., Yap G.P.A., Xie R.H., Khan A.T., Dey K., (2008), An attempt towards coordination supramolecularity from Mn(II), Ni(II) and Cd(II) with a new hexadentate [N4O2] symmetrical Schiff base ligand: Synthesis, crystal structures, electrical conductivity and optical properties, Polyhedron 27 (2008) 3359–3370

DOI: 10.1016/j.poly.2008.07.034

Google Scholar

[7] Tuncel M., Ozbulbul A., Serin S. (2008) Synthesis and characterization of thermally stable Schiff base polymers and their copper(II), cobalt(II) and nickel(II) complexes. Reactive & Functional Polymers 68 (2008) 292-306.

DOI: 10.1016/j.reactfunctpolym.2007.08.012

Google Scholar