Facile Synthesis of Substituted Tetracyanocyclopropanes via Cyclopropanation of Olefin with Arsonium Ylides

Chang Qing Wang; Hai Gen Li; Huai Bo Zou; Hui Liang; Zhi Xing Xiong; Guang Quan Mei

doi:10.4028/www.scientific.net/AMR.554-556.755

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 554-556Facile Synthesis of Substituted...

Facile Synthesis of Substituted Tetracyanocyclopropanes via Cyclopropanation of Olefin with Arsonium Ylides

Abstract:

A facile and efficient methodology for the preparation of 3-aryl-1,1,2,2-tetracyanocyclopropanes is described. Arsonium bromides 2 reacted with benzylidenemalononitriles 1 in the presence of KF•2H2O to provide 3-aryl substituted tetracyanocyclopropanes 3 in high to excellent yields.

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Advanced Materials Research (Volumes 554-556)

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755-759

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.554-556.755

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Online since:

July 2012

Authors:

Chang Qing Wang, Hai Gen Li, Huai Bo Zou, Hui Liang, Zhi Xing Xiong, Guang Quan Mei

Keywords:

Arsonium Ylide, Benzylidenemalononitriles, Cyclopropanes, Tetracyanocyclopropanes

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