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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 554-556Synthesis of Chiral Polysiloxane via...

Synthesis of Chiral Polysiloxane via Hydrosilylation between Synthesized Hydrogen-Containing Polysiloxane and a Chiral Unsaturated Amide

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Abstract:

In this article, we synthesized some hydrogen-containing polysiloxanes by ring-openging polymerization of cyclosiloxanes and studied their viscosity-average molecular weights (η) and active hydrogen content respectively. Then we prepared a chiral amide compound by condensation reaction of acryloyl chloride and (1S)-1-phenylethanamine. Subsequently, we successfully carried out hydrosilylation reaction with the chiral amide and one of hydrogen-containing polysiloxane. In addition, the structures of the target molecules have been confirmed by IR and 1H NMR spectra, elemental analysis and polarimetric analysis.

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Advances in Chemistry Research II

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Periodical:

Advanced Materials Research (Volumes 554-556)

Pages:

801-806

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.554-556.801

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Online since:

July 2012

Authors:

Xiao Ning Zhang, Jin Shui Yao, Xi Jun Sun

Keywords:

Active Hydrogen Content, Chiral Polymers, Hydrogen-Containing Polysiloxanes, Hydrosilylation, N-[(1S)-1-Phenylethyl]prop-2-Enamide, Viscosity-Average Molecular Weights

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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