Study on Novel Structure of Nitric Acid Phenanthroline Vanadium Monohydrate: [ V(C12H8N2) ·O2·(H2O)]·NO3·H2O

Hai Xing Liu; Jing Zhong Xiao; Lan Xu; Vitor Hugo Nunes Rodrigues; Manuela Ramos Marques da Silva; Xi Shi Tai

doi:10.4028/www.scientific.net/AMR.554-556.852

Paper Titles

Synthesis of O-Nitrophenylacetaldehyde
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Efficient and Convenient Preparation of γ-Unsecalactone
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Sythesis and Characterization of Novel Discotic D-A-D System Composed of Perylene Diimide and Thiophene
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Synthesis and Characterization of Hard Hydrolytic Borate Ester Surfactant
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Study on Novel Structure of Nitric Acid Phenanthroline Vanadium Monohydrate: [ V(C₁₂H₈N₂) ·O₂·(H₂O)]·NO₃·H₂O
p.852

The Synthesis and Ion-Exchange Property of Li⁺ Memorized Spinel Li₂Mn_0.75Ti_0.25O₃
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Synthesis of Spinel Li₂MnO₃ and its Ion-Exchange Property for Li⁺
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Synthesis of Quaternary Ammonium Salt Cationic Surfactant with Long-Chain Alkyl and Epoxy Groups
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Improved Preparation of 2,2-Dithiobis(Pyridine-N-Oxide)
p.868

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Study on Novel Structure of Nitric Acid Phenanthroline Vanadium Monohydrate: [ V(C₁₂H₈N₂) ·O₂·(H₂O)]·NO₃·H₂O

Abstract:

A new vanadium complex [ V(C₁₂H₈N₂) ·O₂·(H₂O)]·NO₃·H₂O h as been synthesized from a simple reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. Monoclinic, P2(1)/c. a = 9.5137(2) Å b = 19.3181(4) Å c = 7.51800(10) Å α=γ=90 β= 93.6830. V= 1378.85(4) Å3. Z=2. Rgt(F) = 0.0255, wRref(F2) = 0.0809. T= 273(2) K. The compound consisted of a [ V(C₁₂H₈N₂) ·O₂·(H₂O)]+ cation, one NO₃^- anion and one water molecular. Molecule structure is stabilized by OHN , OHO intramolecular and intermolecular hydrogen bonds.