Effect of Supercritical Carbon Dioxide on the Mechanical Properties and the Morphology of PPO/POE Blends

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Abstract:

Blending PPO and POE-g-MAH assisted by SCCO2 has been investigated. The in-line rheological behavior of PPO and POE-g-MAH containing SCCO2 were studied with the slit die and self made in line rheological testing system. The effect of SCCO2 on the reduction of shear viscosity of PPO is more obvious than that of POE-g-MAH. The shear viscosity of PPO reduced 36.7% with addition 4wt% CO2. Morphology of blends was inspected by SEM. The sizes of POE-g-MAH disperse phase decreased with the contents of CO2 increasing. As a result, the impact strength of blend is improved from 43.5KJ/m2 to 100.9KJ/m2 due to introduce 4wt% SCCO2 for PPO/POE-g-MAH (85/15) blends.

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Periodical:

Advanced Materials Research (Volumes 562-564)

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19-22

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August 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] L. Gerhardt, C.W. Manke, and E. Gulari, Journal of Polymer Science Part B: Polymer Physics, 35, 3(1997).

Google Scholar

[2] A. Garg, E. Gulari, and C.W. Manke, Marcomolecules, 27, 20(1994).

Google Scholar

[3] J.S. Chiou, J.W. Barlow and D.R. Paul, Journal of Applied Polymer Science, 30, 2633(1985).

Google Scholar

[4] M. D. Elkovitch, D. L. Tomasko, and L. J. Lee, Polymer Engineering and Science 39(10), 2075-2084 (1999).

Google Scholar

[5] M. D. Elkovitch, L. J. Lee, and D. L. Tomasko, Polymer Engineering and Science 41(12), 2108-2125 (2001).

Google Scholar

[6] M. D. Elkovitch, L. J. Lee, and D. L. Tomasko, Polymer Engineering and Science 40(8), 1850-1861 (2000).

Google Scholar

[7] Minhee Lee, Costas Tzoganakis, Advances in Polymer Technology 19(4): 200-311(2000).

Google Scholar

[8] Xie Xingyang Xin Chunling He Yadong, China Plastics 22(6): 77-80(2008).

Google Scholar

[9] Hongbo Li, the effect of interfacial tension in CO2 assisted polymer processiong, PHD dissertation, Ohio State University(2004).

Google Scholar