Synthesis and Characterization of Novel Polymer of Vinyl Carbazole Bearing Thiophene Groups

Yun Xian Yang; Ji Ping Yang; Bing Zhou; Jing Yu Zhang

doi:10.4028/www.scientific.net/AMR.562-564.512

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 562-564Synthesis and Characterization of Novel Polymer of...

Synthesis and Characterization of Novel Polymer of Vinyl Carbazole Bearing Thiophene Groups

Abstract:

Combination of vinyl carbazole and thiophene groups’ excellent thermal properties and optical properties, a novel polymer named poly(2,7-bi-2-thienyl-9-vinyl-9-H-carbazole) was synthesized via radical polymerization and Suzuki reaction. The polymer was characterized using Fourier transform infrared spectrometer(FT-IR), gel permeation chromatography(GPC), differential scanning calorimetry(DSC), and X-Ray fluorescence spectrometer(XRF). It was found that this π-conjugated polymer containing vinyl carbazole and thiophene groups gave a high glass transition temperature (Tg=251°C). This feature made poly(2,7-bi-2-thienyl-9-vinyl-9-H-carbazole) possessing an excellent thermal performance.

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Periodical:

Advanced Materials Research (Volumes 562-564)

Pages:

512-515

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.562-564.512

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Online since:

August 2012

Authors:

Yun Xian Yang, Ji Ping Yang, Bing Zhou, Jing Yu Zhang

Keywords:

Polymer, Suzuki, Thiophene, Vinyl Carbazole

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