Research on Oxyfluoride Glasses in Material Engineering with Optical Basicity and Electronic Polarizability

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In material engineering, oxyfluoride glasses have a great important potential application in NLO. The optical basicity and electronic polarizability of oxyfluoride glasses have been evaluated on the basis of the optical electronegativity. The estimated values are in good agreement with previous experimental values. Furthermore, we introduce optical electronegativity of oxyfluoride glasses to predict the glass transition temperature Tg of oxyfluoride glasses. The present investigation suggests that the glass transition temperature Tg decreases with increasing optical electronegativity.

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336-339

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September 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] J. A. Duffy, J. Phys. C: Solid State Phys. Vol. 13 (1980), p.2979.

Google Scholar

[2] J. A. Duffy, J. Solid State Chem. Vol. 62 (1986), p.145.

Google Scholar

[3] R. R. Reddy and Ahammed Y. N. Cryst. Res. Technol. Vol. 30 (1995), p.263.

Google Scholar

[4] R. R. Reddy, Y. N. Ahammed, K. R. Gopal and D. V. Ragharam, Opt. Mater. Vol. 10 (1998), p.95.

Google Scholar

[5] R. R. Reddy, Y. N. Ahammed, K. R. Gopal, P. A. Azeem, D. V. Ragharam and T. V. R. Rao, J. Magn. Magn. Mater. Vol. 192 (1999), p.516.

Google Scholar

[6] J. A. Duffy and M. D. Ingram, J. Am. Chem. Soc. Vol. 93 (1971), p.6448.

Google Scholar

[7] J. A. Duffy and M. D. Ingram, J. Non-Cryst. Solids Vol. 21 (1976), p.373.

Google Scholar

[8] F. G. K Baucke and J. A. Duffy, Phys. Chem. Glass Vol. 32 (1991), p.211.

Google Scholar

[9] A. J Easteal and D. J. Udy, Phys. Chem. Glass Vol. 24 (1983), p.107.

Google Scholar

[10] V. Dimitrov and S. Sakka, J. Appl. Phys. Vol. 79 (1996), p.1736.

Google Scholar

[11] V. Dimitrov and S. Sakka, J. Appl. Phys. Vol. 79, (1996), p.1741.

Google Scholar

[12] X. Y. Zhao, X. L. Wang, H. Lin and Z. Q. Wang, Phys. B Vol. 403 (2008), p.2450.

Google Scholar

[13] X. Y. Zhao, X. L. Wang, H. Lin and Z. Q. Wang, Phys. B Vol. 403 (2008), p.1787.

Google Scholar

[14] L. L. Velli, , C. P. E. Varsamis and Kamitsos, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B Vol. 49 (2008), p.182.

Google Scholar

[15] X. Y. Zhao, X. L. Wang, H. Lin and Z. Q. Wang, Physica B Vol. 392 (2007), p.132.

Google Scholar

[16] X. Y. Zhao, X. L. Wang, H. Lin and Z. Q. Wang, Physica B Vol. 390 (2007), p.293.

Google Scholar

[17] X. Y. Zhao and X. L. Wang, Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B Vol. 50 (2009), p.332.

Google Scholar

[18] X. Y. Zhao, X. L. Wang, H. Lin and Z. Q. Wang, Physica B Vol. 283 (2010), p.1668.

Google Scholar

[19] J. C. Phillips, Phys. Rev. Vol. 166 (1968), p.832.

Google Scholar

[20] J. A. Van Vechten, Phys. Rev. Vol. 182 (1969), p.891.

Google Scholar

[21] B. F. Levine, Phys. Rev., B Vol. 7 (1973), p.2591.

Google Scholar