Synthesis and Crystal Structure of Phosphorus Vandium Heteropolyacid Sodium

Hai Xing Liu; Jing Zhong Xiao; Jing Wang; Fang Fang Jian; Hui Juan Yue; Xi Shi Tai

doi:10.4028/www.scientific.net/AMR.569.103

Paper Titles

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Synthesis and Crystal Structure of Phosphorus Vandium Heteropolyacid Sodium
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 569Synthesis and Crystal Structure of Phosphorus...

Synthesis and Crystal Structure of Phosphorus Vandium Heteropolyacid Sodium

Abstract:

phosphorus vandium heteropolyacid sodium, H₇₈N₁₂NaO₁₁₆P₂V₃₀, is prepared by the hydrothermal method. Cubic, Fm-3m. a =b = c = 20.022(2) Å α=β=γ= 90. V=10680.0(17) Å³. Z=4. R1 =0.0388, wR2 =0.1200. T=298(2) K. The V atoms are linked with O atom bridge. The molecular structure is stabilized by the O-H...O and O-H...N intermolecular and intramolecular hydrogen-bond interaction.

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Periodical:

Advanced Materials Research (Volume 569)

Pages:

103-106

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.569.103

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Online since:

September 2012

Authors:

Hai Xing Liu, Jing Zhong Xiao, Jing Wang, Fang Fang Jian, Hui Juan Yue, Xi Shi Tai

Keywords:

Hydrogen-Bond Interaction, Structure Analysis, Vandium Heteropolyacid

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