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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 583Reaction Kinetics and Optical Storage Characters...

Reaction Kinetics and Optical Storage Characters of a New Diarylethene Materials with Composite Properties

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Abstract:

Photochromism; Diarylethene materials; Fluorecence; Reaction kinetics. Abstract. A new unsymmetrical photochromic diarylethene, 1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(4-formyl-phenyl)-3-thienyl]perfluorocyclopentene (1a), was synthesized, and its photochromic properties and reaction kinetics were investigated, respectively. The compound exhibited good photochromism both in solution and in PMMA film with alternating irradiation by UV/Vis light. The cyclization processes of compound 1a belong to the zeroth order reaction, while the cycloreversion processes belong to the first order reaction. The optical recording results indicated that the new photochromic diarylethene can be applied in high capacity optical storage.

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Advanced Composite Materials and Manufacturing Engineering

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Periodical:

Advanced Materials Research (Volume 583)

Pages:

105-108

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.583.105

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Online since:

October 2012

Authors:

Shi Qiang Cui, Yan Hua Yang, Shou Zhi Pu

Keywords:

Diarylethene Materials, Fluorescence, Photochromism, Reaction Kinetics

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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