CeO2/TiO2 Nanotubes Composites: Synthesis, Characterization, and Photocatalytic Properties

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TiO2 nanotubes were prepared via a hydrothermal route. CeO2 nanoparticles with diameters around 5nm were loaded onto the surface of TiO2 nanotubes via a deposition approach followed by a calcination process. Transmission electron microscopy (TEM), X-ray diffraction (XRD), and UV-vis diffuse reflectance spectroscopy (UV-vis) were applied for the characterization of the as-prepared CeO2/TiO2 nanotubes composites. The results show that CeO2 particles are highly dispersed on the surface of TiO2 nanotubes. The TiO2 nanotubes are modified to response to the visible light due to the combination with CeO2. The CeO2 /TiO2 nanotubes composites with a CeO2 /TiO2 atomic ratio of 2.5% show a further improvement on the photocatalytic activity for degradation of Rhodamine B in water. The presence of CeO2 improves the light absorption of TiO2 nanotubes and inhibits the electron-hole recombination.

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86-90

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October 2012

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] X. Chen, and S. S. Mao: Chem. Rev. Vol. 2891 (2007), p.107.

Google Scholar

[2] G. K. Mor, K. Shankar, M. Paulose, O. K. Varghese, and C. A. Grimes: Nano Lett. Vol. 5 (2005), p.191.

Google Scholar

[3] M. S. sander, M. J. Cote, W. Gu, B. M. Kile, and C. P. Tripp: Adv. Mater. Vol. 16 (2004), p. (2052).

Google Scholar

[4] H. Li, X. Duan, G. Liu, and L. Li: Mater. Res. Bull. Vol. 43 (2008), p. (1971).

Google Scholar

[5] A. Kukovecz, M. Hodos, E. Horva´th, G. Radno´czi, Z. Ko´nya, and I. Kiricsi: J. Phys. Chem. B Vol. 109 (2005), p.17781.

Google Scholar

[6] J. -Z. Xu, W. -B. Zhao, J. -J. Zhu, G. -X. Li, and H. -Y. Chen: J. Colloid. Interf. Sci. Vol. 290 (2005), p.450.

Google Scholar

[7] M. Nolan, S. C. Park and G. W. Watson: J. Phys. Chem. B Vol. 110(2006), p.2256.

Google Scholar

[8] S. Carrettin, P. Concepcion, A. Corma, J. M. N. Lopez and V. F. Puntes: Angew. Chem. Int. Ed. Vol. 43(2004), p.2538.

Google Scholar

[9] N. Ozer: Sol Energy Mater Sol Cells Vol. 68(2001), p.391.

Google Scholar

[10] G. Magesh, B. Viswanathan, R. P. Viswanath, and T. K. Varadarajan: Indian J. Chem. Vol. 48A(2009), p.480.

Google Scholar

[11] Z. -Y. Yuan, and B. -L. Su: Colloids Surfaces A. Vol. 241(2004), p.173.

Google Scholar

[12] X.H. Wang, J.G. Li, and H. Kamiyama: J. Am. Chem. Soc. Vol. 127 (2005), p.10982.

Google Scholar