Influences of Hydrolysis Temperature and Hydrolysis Time on Titanium White Pigment via Short Sulfate Process

Abstract:

Using low concentration TiOSO₄ as titanium raw material, anatase white pigment was prepared by self seeded thermal hydrolysis route via short sulfate process. The effects of hydrolysis temperature and hydrolysis time on the structure and pigment properties of the as-prepared samples were investigated. The samples were characterized by XRD, particle size distribution and pigment properties test. The hydrolysis temperature and time had great effects on the hydrolysis rate, particle size distribution, crystal growth and particle aggregation of TiO₂, eventually determined the pigment structure and its pigment properties. The optimized hydrolysis temperature was at faint boiling point, and the hydrolysis time after second boiling point was of 2.5h. Anatase white pigment was appropriate particle size, narrow particle size distribution and good pigment properties.

• Periodical: Advanced Materials Research (Volumes 602-604)
• Pages: 1255-1260
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.602-604.1255
• Online since: December 2012
• Authors: Cong Xue Tian, Shuang Hua Huang, Ying Yang
• Keywords: Hydrolysis Temperature, Hydrolysis Time, Short Sulfate Process, TiOSO₄

References

[1] Tioxide Group Limited: Manufacture and General Properties of Titanium Dioxide Pigments, London, 1992.

[2] E. Santacesaria, M. Tonello, G. Storti, R. C.Pace, S. Carra: J Colloid Interface Sci. Vol. 111 (1986), p.44

[3] Z. L. Tang: Production and environmental treatment of titanium dioxide. Peking: Chem. Ind. Press, 2000.

[4] J. Z. Zhao, Z. C. Wang, L.W. Wang: Mater. Chem. Phy. Vol. 63(2000), p.9

[5] W. Hixson, C.Ralphe: Ind. Eng. Chem. Vol. 37 (1945), p.678

[6] H. Becker, E. Klein, H. Rechmann: Chem. Eng. J. Vol. 70(1964), p.779

[7] R. G. Richards, J. F. Duncan: New Zeal. J. Sci. Vol. 19(1976), p.179

[8] E.Santacesatia: J of Colloid Interf. Sci. Vol. 111 (1986), p.45

[9] S. Sathyamoorthy, M. J. Hounslob, G. D.Moggridge: Journal of Cryst. Growth Vol. 223 (2001), p.225

[10] B. U. Grzmil, D. Grela, B. Kic: Chemical Pap. Vol. 63 (2008), p.18

[11] B. U.Grzmil, D.Grela, B. Kic: Pol. J. Chem. Technol. Vol. 11 (2009), p.15

[12] I. Szilagyi, E. Konigsberger, P. M. May: Inorg. Chem. Vol. 48 (2009), p.2200

[13] B. U. Grzmil, D. Grela, B. Kic: Chemical Pap. Vol. 63(2009), p.217

[14] M. Sgraja, J. Blomer, J. Bertling, P. J. Jansens: Chem. Eng. J. Vol. 160(2000), p.351

[15] SIR SOC ITAL RESINE SPA, F.R. Patent 2,309,472. (1976)

[16] F. K. Urakaev, L. S. Bazarov, I. N. Meshcheryakov, et al: Colloid J. Vol. 61 (1999), p.647

[17] S. Sathyamoorthy, G. D. Moggridge, M. J. Hounslow: Cryst. Growth Des. Vol. 1 (2001), p.123

[18] C. X. Tian, J. Q. Du, X. H. Chen, W. P. Ma, Z. Q. Luo, X. Z. Cheng, H. F. Hu, D. J. Liu: Trans. Nonferrous Met. Soc. China Vol. S3 (2009), p. S829