Effects of EVA-g-MAH on Mechanical Properties and Morphological Structure of TPU/PVC Blends

Article Preview

Abstract:

The effects of ethylene vinyl acetate grafting maleic anhydride (EVA-g-MAH )as a compatilizer on the mechanical properties, compatibility and morphological structure of thermoplastic Polyurethane and poly(vinyl chloride) blends were studied. The blends were prepared and characterized by mechanics properties test, scanning electron microscopy(SEM,)dynamic mechanical properties (DMA) and thermogravimetry(TG) . Mechanical properties indicate that the hardness, tensile strength, breaking elongation of the blends are greatly improved by EVA-g-MAH, when the critical EVA-g-MAH content at about 4 wt%.SEM micrographs reveal that EVA-g-MAH could bring down the diameter of dispersed , change brittle fracture into ductile fracture, and promote adhesion of phase interface. The glass transition temperature change by DMA proves that the addition of the EVA-g-MAH improved the compatibilization of blends. And the results of TG experiment show that EVA-g-MAH greatly improve the thermal stability of the blends.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 602-604)

Pages:

656-659

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] VJRR Pita, EEM Sampaio , EEC Monteiro. Polymer Testing. 21(2002) , 545~550.

Google Scholar

[2] S . Parnell, K. Min. Polymer . 46(2005) , 3649~3660.

Google Scholar

[3] K. Piehchowski, I. Hamerton. European Polymer Journal. 36 (2000) , 171~181.

Google Scholar

[4] O. Revjakin,J. Zicans,M. Kalnins and A.K. Bledzky. Polymer International. 49 (2000) , 917~920.

DOI: 10.1002/1097-0126(200009)49:9<917::aid-pi377>3.0.co;2-m

Google Scholar

[5] K.H. Lee H.Y. Kim Y.J. Ryu. etc. Journal of Polymer Science. 41(2003) , 1256~1262.

Google Scholar