For Libraries For Publication Open Access Downloads About Us Contact Us
Paper Titles
Effects of EVA-g-MAH on Mechanical Properties and Morphological Structure of TPU/PVC Blends
p.656
Synthesis and Characterization of a New Kind of UV-Curable Cyclohexanone-Formaldehyde Resins
p.660
Polyurethane Application in a Large-Scale LNG Tank
p.664
Study on Inhibition of Water Tree in XLPE Insulation Material
p.668
Study the Influences of ZnEt2 on Ethylene Chain Transfer Polymerization
p.672
An Orthogonal Experiment of Bagasse Cellulose Dissolution in Ionic Liquid by Microwave Heating
p.676
Time-Temperature-Stress Superposition Principle: Brief Description and Application to Polymer Creep Behavior
p.681
Study on Layered Structure and Properties of PP/LLDPE Injection Molding
p.685
Effect of Curing System on Morphological, Rheological, Thermal and Mechanical Properties of Thermoplastic Vulcanizates Based on Epoxidized Natural Rubber and Polypropylene
p.690

Study the Influences of ZnEt2 on Ethylene Chain Transfer Polymerization

Article Preview

Abstract:

The influences of ZnEt2 on ethylene chain transfer polymerization were investigated in detail and the polymerization mechanism was thoroughly analyzed. The results indicated that ZnEt2 contributed greatly to increase the activity of α-diimine nickel complex/ZnEt2/MAO(MAO: methylaluminoxane). It was striking that α-diimine nickel complex/ZnEt2 catalyst system (1/100 mol/mol) exhibited 8.0 ×104g/mol∙h activity, it was possible the formation of the ion pairs of Nickel and Zinc was convenient for ethylene chain propagation, however, the ion pairs were unstable in ethylene polymerization.

You might also be interested in these eBooks
Progress in Materials and Processes View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 602-604)

Pages:

672-675

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.602-604.672

Citation:

Cite this paper

Online since:

December 2012

Authors:

An Guo Xiao, Shi Biao Zhou, Qing Yun Zheng, You Ming Shen, Yong Bin Zhuan

Keywords:

Chain Transfer, Polyethylene, ZnEt2, α-Diimine Nickel Complex

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

References

[1] Britovsek G.J., Cohen S A., Gbison V.C., Meurs M.V. J. Am. Chem. Soc. 2004, 126, 10701-10712.

Google Scholar

[2] Kuhlman R.L., Wenzel T.T. Macromolecules 2008, 41, 4090-4094.

Google Scholar

[3] Zhang W., Sita L.R. J. Am. Chem. Soc. 2008, 130, 442-443.

Google Scholar

[4] Hustad P.D., Kuhlman R.L., Carnahan E.M., Wenzel T.T., Arriola D.J. Macromolecules 2008, 41,4081-4089.

DOI: 10.1021/ma800357n

Google Scholar

[5] Alfano F., Boone H.W., Busico V., Cipullo R., Stevens J.C. . Macromolecule 2007, 40, 7736-7738.

Google Scholar

[6] Arriola D.J., Carnahan E.M., Hustad P.D., Kuhlman R.L., Wenzel T.T. Science 2006, 312, 714-719.

DOI: 10.1126/science.1125268

Google Scholar

[7] Xiao A.G., Wang L., Liu Q.Q., Yu H.J., Wang J.J., Huo J., Tan Q.H., Ding J.J., Ding W.B., and Abid M.A. Macromolecules 2009, 42, 1834-1837.

Google Scholar

[8] Li P., Zhang K.Y., Nishiura M., and Hou Z.M. Angew. Chem. Int. Ed. 2011, 50, 12012-12015.

Google Scholar

[9] Chung T. C. and Dong.J. Y. J. Am. Chem. Soc., 2001,123, 4871-4876.

Google Scholar

[10] Lee J.Y., TSAI J.C. J. Polym. Sci. Part A: Polym.Chem., 2011. 49, 3739–3750.

Google Scholar

[11] Martin.M., George J. P., Vernon C. G, and Steven A. J. Am. Chem. Soc. 2005, 127, 9913-9923

Google Scholar

[12] Isabelle Haas, Winfried P. Kretschmer. Organometallics 2011, 30, 4854–4861

Google Scholar

© 2025 Trans Tech Publications Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies. For open access content, terms of the Creative Commons licensing CC-BY are applied.
Scientific.Net is a registered trademark of Trans Tech Publications Ltd.