Preparation of Silicalite-1 Membranes on α-Al2O3 Tubes and its Concentration Performance of Low Ethanol/water Mixtures

Hong Liang Chen; Ji Song Yang; Yan Wang; Hui Ying Li; Xin Xin Li; Wei Shen Yang

doi:10.4028/www.scientific.net/AMR.608-609.1337

Paper Titles

Effect of Annealing Temperature on Electrical Properties of ZnTe Layers Grown by Thermal Evaporation
p.1314

Preparation and Properties of PEDOT/PSS Conductive Polymer Blended with Graphene/PVDF
p.1318

Study on Composite of Porous Si and Disordered Carbon as Anode Materials for Lithium Ion Batteries
p.1327

Excess Heat Triggered by Electrical Current in a D/Pd Gas-Loading System
p.1331

Preparation of Silicalite-1 Membranes on α-Al₂O₃ Tubes and its Concentration Performance of Low Ethanol/water Mixtures
p.1337

Effect of Synthesis Process of Polyaniline for the Zn-PANi Secondary Batteries
p.1342

Impact of Substitution of M (M=Mn, Cu) for Ni on Hydriding and Dehydriding Kinetics of as-Spun Nanocrystalline and Amorphous Mg₂Ni-Type Alloys
p.1347

Preparation of PET/PT Composite Film and Study of its Moisture Barrier Properties
p.1351

Luminescent Layer by Layer Thin Films Based on Polyoxometalate and Poly(amidoamine) Dendrimer
p.1354

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 608-609Preparation of Silicalite-1 Membranes on α-Al2O3...

Preparation of Silicalite-1 Membranes on α-Al₂O₃ Tubes and its Concentration Performance of Low Ethanol/water Mixtures

Abstract:

Silicalite-1 membranes were successfully synthesized on α-Al₂O₃ tubes by in-situ hydrothermal synthesis after filling the tubes with water and glycerol mixtures, and all the membranes show high concentration performance towards ethanol/water mixtures after pretreating tubes with different NaOH solution. The results show that the flux enhances with the enhancement of NaOH solution concentration, but the separation selectivity decreases with the enhancement of NaOH solution concentration. After pretreating the α-Al₂O₃ tubes with different NaOH solution, the weight of all the α-Al₂O₃ tube decreases, but the Si/Al ratio increases, which shows that suitable pretreatment of α-Al₂O₃ is useful for improving the hydrophobicity of silicalite-1 membranes.

You might also be interested in these eBooks

View Preview

Progress in Renewable and Sustainable Energy

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 608-609)

Pages:

1337-1341

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.608-609.1337

Citation:

Cite this paper

Online since:

December 2012

Authors:

Hong Liang Chen, Ji Song Yang, Yan Wang, Hui Ying Li, Xin Xin Li, Wei Shen Yang

Keywords:

Pretreatment, Silicalite-1 Membrane, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] F. W. Bai, W. A. Anderson, M. Moo-Young，Ethanol fermentation technologies from sugar and starch feedstocks, Biotechnology Advances, 26 (2008) 89.

DOI: 10.1016/j.biotechadv.2007.09.002

Google Scholar

[2] J. Caro, M. Noack, Zeolite membranes – Recent developments and progress, Micropor.Mesopor. Mater., 115 (2008) 215.

Google Scholar

[3] M. Gualtieri, C. Andersson, F. Jareman, J. Hedlund, A. F. Gualtieri, M. Leoni, C. Meneghini, Crack formation in α-alumina supported MFI zeolite membranes studied by in situ high temperature synchrotron powder diffraction，J.Memb. Sci., 290 (2007) 95.

DOI: 10.1016/j.memsci.2006.12.018

Google Scholar

[4] S. Aguado, E. E. McLeary, A. Nijmeijer, M. Luiten, J. C. Jansen, F. Kapteijn, b-Oriented MFI membranes prepared from porous silica coatings, Micropor. Mesopor. Mater., 120 (2009) 165.

DOI: 10.1016/j.micromeso.2008.08.059

Google Scholar

[5] X. Lin, H. Kita, K. Okamoto, Silicalite membrane preparation, characterization, and separation performance, Ind. Eng. Chem. Res., 40 (2001) 4069.

DOI: 10.1021/ie0101947

Google Scholar

[6] Y. Liu, Y. Li, W. Yang, Fabrication of highly b-oriented MFI film with molecular sieving properties by controlled in-plane secondary growth, J. Am. Chem. Soc., 132 (2010) 1768.

DOI: 10.1021/ja909888v

Google Scholar

[7] Y. Yan, M.E. Davis, G.R. Gavalas, Use of diffusion barriers in the preparation of supported zeolite ZSM-5 membranes, J. Membr. Sci., 126 (1997) 53.

DOI: 10.1016/s0376-7388(96)00263-3

Google Scholar

[8] J. Hedlund, J. Sterte, M. Anthonis, A.J. Bons, B. Carstensen, N. Corcoran, D. Cox, H. Deckman, W.D. Gijnst, P.P. de Moor, F. Lai, J. McHenry,W. Mortier, J. Reinoso, J. Peters, High-flux MFI membranes, Micropor. Mesopor. Mater., 52 (2002) 179.

DOI: 10.1016/s1387-1811(02)00316-5

Google Scholar

[9] H. Chen, Y. Li, W. Yang, Preparation of silicalite-1 membrane by solution-filling method and its alcohol extraction properties, J. Membr. Sci., 296 (2007) 122.

DOI: 10.1016/j.memsci.2007.03.021

Google Scholar