Effect of PH on the Performance of the Anode in Microbial Fuel Cells

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Abstract:

Microbial fuel cells with microbial brush anode and ferricyanide-cathode which could discharge at current up to 350 mA were constructed, and the effect of anodic pH on the performance of the microbial anode was investigated in the present study. Anodic pH was found to decrease significantly, from 6.23 to 4.35, when the MFC was operated to discharge at high current levels, which in turn reduced the performance of the microbial anode. No obvious pH change was observed during MFC discharge at lower current level (~12 mA), meaning that proton production is mainly related to the electrochemical oxidization of the organic fuels, rather than to the microbial degradation in the anode chamber. Results presented herein indicate that effective approach should be employed to control the anodic pH close to neutral conditions when optimizing the power output of microbial fuel cells, especially at high discharge current.

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Periodical:

Advanced Materials Research (Volumes 608-609)

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884-888

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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