Synthesis and Bioactivities of Poly N-Arenely-N’- (1,4-Butenelydioxycarbonyl)thioureas

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Abstract:

Four novel poly N-Arenely-N’-(1,4-butenelydioxycarbonyl)thioureas (3a~d) were synthesized by the reaction of aryldiamines with 1,4-butenlydioxycarbonyl diisothiocyanate. Their structures were characterized by IR spectra and gel permeation chromatography(GPC). The preliminary biological activity tests showed that some compounds display effect in growth regulation of plants and fungicidal activity to some extent. The compound 3a has excellent effect in growth regulation of plants, and its promotion ratio to Oryza sativa L.(rice) is 64.8% in dosage of 80 mg/L, its inhibition ratio to Echinochloa crus-galli L.(barnyard grass) is 83.2% in dosage of 60 mg/L. The antibacterial tests indicated that the title compounds have poor fungicidal activities using Gibberella zeae, Fusarium oxysporium, Magnaporthe oryzae, Rhizoctonia solani, and Sclerotinia sclerotiorum as target fungi, but only did the compound 3a have a comparatively well antifungal activities against F. oxysporium and S. Sclerotiorum, and its inhibition ratios are 38.8% and 30.9% at 100mg/L, respectively.

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Advanced Materials Research (Volumes 610-613)

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177-180

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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