Hydrothermal Preparation, Characterization and Photocatalytic Properties of C, N Co-Doped ZnO/ZnS Composites

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Abstract:

C, N, S co-doped ZnO/ZnS composites were prepared by hydrothermal method using ZnSO4 and L-cysteine as raw materials, and investigated by UV-vis DRS, XRD, XPS. The results showed that C, N, S have successfully doped onto ZnO and substituted O of crystal lattice during hydrothermal process. The resulting co-doped ZnO composites exhibit significantly higher photocatalytic activity (45%) than that of pure ZnO (<5%) for degradation of reactive brilliant blue KN-R aqueous solution under simulative solar irradiation. The enhancement of photocatalytic performance of co-doped composites can be attributed to the reducing of electron-hole pair recombination and narrowed band gap.

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Advanced Materials Research (Volumes 610-613)

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1841-1844

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] D. Li, H. Haneda, Morphologies of zinc oxide particles and their effects on photocatalysis, Chemosphere 51 (2003) 129-137.

DOI: 10.1016/s0045-6535(02)00787-7

Google Scholar

[2] C. Hariharan, Photocatalytic degradation of organic contaminants in water by ZnO nanoparticles: Revisited, Appl. Catal. A: Gen. 304 (2006) 55-61.

DOI: 10.1016/j.apcata.2006.02.020

Google Scholar

[3] T.G. Xu, L.W. Zhang, H.Y. Cheng, Y.F. Zhu, Significantly enhanced photocatalytic performance of ZnO via graphene hybridization and the mechanism study, Appl. Catal. B 101 (2011) 382-387.

DOI: 10.1016/j.apcatb.2010.10.007

Google Scholar

[4] V.K. Pareek, A.A. Adesina, Handbook of Photochemistry and Photobiology 1 (2003) 345-412.

Google Scholar

[5] A.W. Xu, Y. Gao, H.Q. Liu, The preparation, characterization, and their photocatalytic activities of rare-earth-doped TiO2 nanoparticles, J. Catal. 207 (2002) 151-157.

DOI: 10.1006/jcat.2002.3539

Google Scholar

[6] L.Q. Jing, X.J. Sun, B.F. Xin, B.Q. Wang, W.M. Cai, H.G. Fu, The preparation and characterization of La doped TiO2 nanoparticles and their photocatalytic activity, J. Solid State Chem. 177 (2004) 3375-3382.

DOI: 10.1016/j.jssc.2004.05.064

Google Scholar

[7] D. Li, H. Haneda, Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition, J. Photochem. Photobiol. A: Chem. 155 (2003) 171-178.

DOI: 10.1016/s1010-6030(02)00371-4

Google Scholar

[8] J.S. Jang, C.J. Yu, S.H. Choi, S.M. Ji, E.S. Kim, J.S. Lee, Topotactic synthesis of mesoporous ZnS and ZnO nanoplates and their photocatalytic activity, J. Catal. 254 (2008) 144-155.

DOI: 10.1016/j.jcat.2007.12.010

Google Scholar

[9] J.G. Ma, Y.C. Liu, R. Mu, J.Y. Zhang, Y.M. Lu, D.Z. Shen, X.W. Fan, Method of control of nitrogen content in ZnO films: Structural and photoluminescence properties, J. Vac. Sci. Technol. B 22 (2004) 94-98.

DOI: 10.1116/1.1641057

Google Scholar

[10] J.C. Yu, W.K. Ho, J.G. Yu, H. Yip, P.K. Wong, J.C. Zhao, Efficient visible-light-induced photocatalytic disinfection on sulfur-doped nanocrystalline Titania, Environ. Sci. Technol. 39 (2005) 1175-1179.

DOI: 10.1021/es035374h

Google Scholar