Synthesis and Characterization of Cyclic Carbonate from CO₂

Abstract:

(2-oxo-1,3-dioxolan-4-yl)methyl-2-methylprop-2-enoate (DOMA) was synthesized from glycidyl methacrylate (GMA) and carbon dioxide, which can be further polymerized into water-based non-isocyanate polyurethane(NIPU). The structure of DOMA was characterized by IR spectra, 1H-NMR and 13C-NMR analysis. The effects of the catalysts, reaction temperature, pressure and duration on the yield of DOMA were enquired in detail. It was shown that TBAB and ZnI2 used as catalysts, reaction temperature, pressure and duration set as 110°C, 1.2 MPa and 4 hr respectively, the yield could reach 76.5%.

• Periodical: Advanced Materials Research (Volumes 610-613)
• Pages: 542-546
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.610-613.542
• Online since: December 2012
• Authors: Wu Ying Zhang, Hong Bo Liu, Feng Lin
• Keywords: Carbon Dioxide, Cyclic Carbonate, Glycidyl Methacrylate

References

[1] Chungu Xia, Linfei Xiao, Jing Chen: P. CN101037431A. In Chinese

[2] Tamami B, Sohn S,Wilkes G L:J. Appl. Polym. Sci.Vol. 92(2004), pp.883-891

[3] V.Stone: P. CN1543458A. In Chinese

[4] Oleg L. Figovsky: P. US, 6120905, 2000-9-19.

[5] Tomishige K, Yasuda H, et al. : J . Green Chem. Vol. 6(2004), pp.206-214

[6] Shiyong Huang,Shui-gang Liu,Junping Li,et al. J . Catal .Lett.Vol.112(2006), pp.187-191

[7] Dongsheng Bai, Xiaoxuan Wang,Yingying Song: J .Catal.Vol. 31(2010), pp.176-180. In Chinese

[8] Sachin R. Jagtap, Mayur J. Bhanushali, Anil G. Panda, et al: Catal .Lett.Vol.112(2006), pp.51-55

[9] Xi Zhou, Yi Zhang, Xiangui Yang: J.Catal.Vol.31(2010),pp.765-768 .In Chinese

[10] Maoqing Kang, Yuhua Zhao, Zhenrong Li: P. CN1880360A .In Chinese