Advances in Research of Zinc-Based Sorbent for Coal Gas Desulfurization

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Abstract:

This paper provides a comprehensive overview of the R&D status and advances of the cleaning of hydrogen sulfide from coal gas streams using zinc-based sorbents including ZnO, ZnFe2O4, Zn2TiO4 and supported zinc-based sorbents. The characteristics of single oxides sorbents, complex zinc-base sorbents and supported zinc-based sorbents are compared, including the preparation processes,desulfurization behavior and desulfurization precision, etc. Supported zinc-based sorbents are regarded as prospective sorbents in industrial applications due to their better desulfuization precision and regeneration properties. Char supported zinc-based sorbents have good performance during desulfurization at medium temperatures.

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Advanced Materials Research (Volumes 616-618)

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1853-1859

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Phillip. W. R: Environ. Sci. Technol. Vol. 10(1976), pp.659-661.

Google Scholar

[2] Fu C.: Physical Chemistry. Higher Education Press, Beijing. 1990. In Chinese.

Google Scholar

[3] Information on http://wenku.baidu.com/view/805bd16db84ae45c3b358c4b.html.

Google Scholar

[4] Chen R.: J Ind. Catal. Vol. 2(1994), pp.51-52. In Chinese.

Google Scholar

[5] Li H., Zhang H. and Tang P.:J Qilu Petrochem Technol. Vol.32(2004), pp.100-102. In Chinese.

Google Scholar

[6] Evangelos A., Efthimiadis E. A. and Stratis V.: Chem. Eng. Sci. Vol. 48(1993), pp.829-843.

Google Scholar

[7] Tamhankar S. S., Bagajewicz M. and Gavalas G. R.: Ind. Eng .Chem. Vol.25 (1986), pp.429-437.

Google Scholar

[8] Eiji S., Shigeru H. and Shigeaki K.: Energy Fuels Vol. 8(1994), pp.763-769.

Google Scholar

[9] Zhang M., Zhang H. and Chen Y.: J Chem. Ind. Eng. Vol. 25(2004), pp.29-31. In Chinese.

Google Scholar

[10] Grinadley. T. and Steinfeld.G.: in 3rd Annual Contractors' Meeting on Contaminant Control in Hot Coal Derived Gas Streams, China(1983).

Google Scholar

[11] Lu Y., Sha Z. , Lu Q., Wu Q. and Peng X.: J Fuel Chem. Technol.Vol.24(1996), pp.492-497. In Chinese.

Google Scholar

[12] Gupta R., Gangwal S.K. and Jain. S.C.: Energy Fuels Vol. 44(1992),pp.21-27.

Google Scholar

[13] Focht. G. D, Ranade .P.V and Harrison .D.P: Chem . Eng . Sci .Vol. 44(1989), pp.2919-2926.

Google Scholar

[14] Wood M .C., Gangwal S.C. and Harrison D.P.: Ind. Eng. Chem. Res. Vol. 30(1991), pp.100-107

Google Scholar

[15] Liu B. , Wang R. , Mi J. : J Shanxi Chem. Ind. Vol. 29(2009),pp.12-15. In Chinese.

Google Scholar

[16] Li F., Li H. , Wang Q.:J Coal Chem. Ind. Vol. 4(1997),pp.34-38. In Chinese.

Google Scholar

[17] Akyurtlu .J. F and Akyurtlu. A : Gas Sep. Purif. Vol. 9(1995),pp.17-25.

Google Scholar

[18] Pineda. M., Palacios. J. M. and Alonso. L.: Fuel Vol. 9(2000),pp.885-895.

Google Scholar

[19] Li Z.H. : Preparation of nanocrystalline zinc titanate powders via precipitation process and their performance .Master thesis .Si Chuan University, 2007.

Google Scholar

[20] Lew. S. ,Sarofim . A. F. and Flytzani-Stephanopoulos. M. :Chem . Eng .Sci. Vol.47(1988),pp.1421-1431.

Google Scholar

[21] Lew .S ,Kandaswami .J. and Flytzani-Stephanopoulos .M.:Ind.Eng.Chem.Res. Vol.28 (1989),pp.535-541.

Google Scholar

[22] Efthimiadis .E. A., Sotirchos .S.V.: Chem. Eng. Sci. Vol. 48 (1993), pp.829-843.

Google Scholar

[23] Xu Y. : Preparation characterization and reactivity testing of zinc ferrite sorbents in the lower temperature range (350-450°C).Master Thesis .Taiyuan University of Technology. 2002.

Google Scholar

[24] Jun. H. K. and Lee. T. J.: Ind. Eng. Chem. Res. Vol. 40(2001),pp.3547-3556.

Google Scholar

[25] Jun. H. K. and Koo .J. H.: Energy Fuels Vol.18(2004),pp.41-48.

Google Scholar

[26] Ryu .S. O. and Kukpar.K. N.: Ind. Eng. Chem. Res. Vol. 43 (2004),pp.334-341.

Google Scholar

[27] Wei N. : Preparation and desulfurization performance of La(Sm)MeOx/SBA-15 for hot coal gas. Mater thesis .Tianjing University.2010.

Google Scholar

[28] Jiang E. , Zhao Y. , Xie C. :J Chemistry Vol.63(2000),pp.25-31. In Chinese.

Google Scholar

[29] F.Toma's and Palacios Latsa.J. M.: Fuel Processing Technol. Vol. 86 (2004),pp.191-203.

Google Scholar

[30] Zhang Y.: Preparation and research of new-type ZnO-based compound desulfurizer .Master Thesis. Harbin Engineering University.(2004)

Google Scholar

[31] Qin M. :Study on sulfidation performance of Zn/Mn/Cu-based sorbent supported on semi-coke in medium temperature coal gas . Master Thesis. Taiyuan University of Technology.2010.

Google Scholar

[32] Wang Y., Guo Q. and Pan W. : J Coal Conv. Vol.33(2010),pp.16-21. In Chinese.

Google Scholar

[33] Cal. M. P.,Stickler. B. W. and Lazio .A. A: Carbon Vol. 38(2000),pp.1758-1765.

Google Scholar

[34] Ikenaga .N-O, Chiyoda. N. and Matsushima. H.: Fuel Vol.81(2002),pp.1569-1576.

Google Scholar

[35] Ikenga. N-O, Ohgaim .Y. and Matsushima .H.: Fuel Vol.83(2004),pp.661-669.

Google Scholar

[36] Zhou H. and Hua Zh. J Hebei Ins .Archit Sci. Techno.Vol. 20(2003),pp.8-10. In Chinese.

Google Scholar

[37] Guo T., Zhang Y. and Mi J.: J Shanxi Chem. Ind. Vol. 30(2010),pp.1-4. In Chinese.

Google Scholar

[38] Liu Y. ,Li H. ,Zhao B.: J Coal conv. Vol.23(2000),pp.26-31.

Google Scholar

[39] Elenkov. M. and M. Dimitur: Erdöl kohle erdgas petrochem. Brennt-chem Vol.25 (1992), pp.248-252.

Google Scholar

[40] Wang R.: The Preparation and reactivity testing of ZnFe2O4/AC hot coal gas desulfurizer .Mater Thesis .Taiyuan University of Technology.2009.

Google Scholar

[41] Zheng R., and Jin M.:J China Coal Soc. Vol.36(2011),pp.1911-1977. In Chinese.

Google Scholar

[42] Khare G. P. , Delzer G. A. and Kubicek D. H.: Environ .Prog. Vol. 14(1995),pp.146-150.

Google Scholar

[43] Wang J., Ying J. and Xu G.: J China Coal Soc. Vol. 21(1996),pp.526-530. In Chinese.

Google Scholar

[44] Deng Y. and Bu P.: J China Coal Soc.Vol.31(2006),pp.223-226.In Chinese.

Google Scholar

[45] Zhang Y.: Preparation of mixed oxide/modified semi-coke desulfurization applied in medium high temperature coal gas clean up. Master Thesis. University Taiyuan University of Technology. 2010.

Google Scholar