Study on Preparation Zeolite X from Stellerite

Article Preview

Abstract:

Natural Stellerite has a big reserve volume, but has some shortcomings which are irregular ducts and Connotation impurities and so on. So, it is necessary to use Stellerite to prepare zeolite X for enhancing purity and property. It tests Products by XRD, FT-IR and Stereo Microscope. The study shows that optimum parameter is n(SiO2)/n(Al2O3)=3, n(Na2O)/n(SiO2) =1.1-1.2 and n(H2O)/ n(Na2O)=30-40. The gel ages at room temperature for 12 h, and then keeps at 95 °C for 7h. The pure zeolite X could be prepared.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

283-286

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] N. Shigemoto, H.Hayashi, M K.iyaura, Selective formation of Na-X zeolite from coal fly ash by fusion with sodium hydroxide prior to hydrothermal reaction, J. Mater. Res. 28(1990) 4781–4786.

DOI: 10.1007/bf00414272

Google Scholar

[2] S.H. Sheng, D.W. Wang, S.G. Zhang, Study on optimization of the technics about using natural stellerite to synthesize zeolite 4A, J. Guilin. Univ. Technol. 21 (2001) 381-385.

Google Scholar

[3] Y.S. Tao, H. Kanoh, A. Abrams, et al. Mesopore-modified zeolites: preparation, characterization, and applications, Chem. Rev. 106 (2006) 896-910.

DOI: 10.1021/cr040204o

Google Scholar

[4] N.C. Chen, Q. Tang, A.P Deng, W. Wang, X.H Zhang, Synthesis of Type-A Zeolite in Hydrothermal Condition with Stellerite, Adv. Mater. Res. 194 (2011) 492-496.

DOI: 10.4028/www.scientific.net/amr.194-196.492

Google Scholar

[5] U. Loshe, I.Pitsch, E.Schreier, B.Parlitz, K.-H.Schnabel, Cubic and hexagonal faujasites with varying Si/ Al ratios I. Synthesis and characterization, Appl. Catal. A-gen. 129 (1995) 189-202.

DOI: 10.1016/0926-860x(95)00092-5

Google Scholar

[6] D.Novembre, B.Di Sabatino, et al. Synthesis of Na–X zeolites from tripolaceous deposits (Crotone, Italy) and volcanic zeolitised rocks (Vico volcano, Italy), Micropor. Mesopor. Mat. 75 (2004) 1-11.

DOI: 10.1016/j.micromeso.2004.06.022

Google Scholar

[7] E.M. Flaningen, H.A. Khatami, H.A. Szymanski, Advances in Chemistry Series no.101 MSZ, J. Am. Chem. Soc. 44 (1972) 201-202.

Google Scholar