Inhibition Effect of Sodium Nitrite and Triethanolamine for Uranium with Electrochemical Methods

Article Preview

Abstract:

The corrosion inhibition effect of sodium nitrite (NaNO2) and triethanolamine (N(C2H4OH)3) for uranium was evaluated in 200 mg/L sodium chloride (NaCl) solution by linear polarization and potentiodynamic polarization. The results showed that NaNO2 predominatly acted to inhibit the anodic reaction for the electrochemical behavior of uranium. NaNO2 combined with N(C2H4OH)3 could reinforce corrosion resistance of uranium. Multi-function could be found from 20 g/L NaNO2 combined with 10 mL/L N(C2H4OH)3. Pitting corrosion on uranium surface could be effectively prevented by 1g/L NaNO2 combined with 10 mL/L N(C2H4OH)3. Auger electron spectroscopy (AES) and Raman spectrum analyses indicated that uranium oxide layer mainly contained uranium dioxide (UO2).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

307-312

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] W.D. Wilkinson, Uranium Metallurgy, Interscience Publishers, New York, 1962.

Google Scholar

[2] J.M. Haschke, Corrosion of uranium in air and water vapor: consequences for environmental dispersal, J. Alloys and Compounds. 278(1998) 149-160.

DOI: 10.1016/s0925-8388(98)00639-2

Google Scholar

[3] J.T. Waber, A review of the corrosion of uranium and its alloys, The Unite State Atomic Energy Committee, 1952.

Google Scholar

[4] D.L. Lake, Approching environmental acceptability in cooling water corrosion inhibition, J. Corrosion prevention and control, 7(1989) 12-13.

Google Scholar

[5] K.K. Sideris, A.E. Savva, Durability of mixtures containing calcium nitrite based corrosion inhibitor, J. Cement & Concrete Composites, 27(2005) 277-287.

DOI: 10.1016/j.cemconcomp.2004.02.016

Google Scholar

[6] J.S. Reoua, K.Y. Ann, The electrochemical assessment of corrosion inhibition effect of calcium nitrite in blended concretes, J. Materials Chemistry and Physics, 109(2008) 526-533.

DOI: 10.1016/j.matchemphys.2007.12.030

Google Scholar

[7] G.D. Schutter, L. Luo, Effect of corrosion inhibiting admixtures on concrete properties, J. Construction and Building Materials, 18(2004) 483-489.

DOI: 10.1016/j.conbuildmat.2004.04.001

Google Scholar

[8] C.K. Nmai, Multi-functional organic corrosion inhibitor, J. Cement & Concrete Composites, 26(2004) 199-207.

DOI: 10.1016/s0958-9465(03)00039-8

Google Scholar

[9] D.B. Alexander, A.A. Maccari, Evaluation of corrosion inhibitors for component cooling water systems, J. Corrosion, 49(1993) 921-928.

DOI: 10.5006/1.3316018

Google Scholar

[10] Q.Y. Wu, The synergism of inhibitors, J. Materials Protection, 29(1996) 16-17.

Google Scholar

[11] Y.S. Wu, J.S. Zheng, Electrochemical protection and inhibitor application, Chemical Industry Press, Perkin, 2006.

Google Scholar

[12] G.C. Allen, L.S. Butler, N.A. Tuan, Characterisation of uranium oxides by micro-raman spectroscopy, J. Nucl Mater, 144(1987) 17-19.

DOI: 10.1016/0022-3115(87)90274-1

Google Scholar