Solidification Behavior of Rapidly Quenched LaFe13-xSix Alloys

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Solidification behavior of LaFe13-xSix alloys was investigated using rapidly quenching and. Phase formation and structure in rapidly quenched LaFe13-xSix alloys has been investigated by means of power X-ray diffraction analysis (XRD) and scanning electron microscopy (SEM). The results have shown that 1:13 phase is a peritectic phase. The solidification behavior of LaFe13-xSix alloys depend on x, cooling rate. Under small undercooling, the 1:13 phase is difficult to formed with x=0.5 to 3.0. The α-(Fe,Si) phase and the 1:2:2 phase is mainly phase in the microstructure of alloy with low and high Si contents, respectively. Under higher cooling rate, the microstructure of compositions with x≥1.5 occurs the 1:13 phase. The α-(Fe,Si) phase and the 1:13 phase is mainly phase in the microstructure of alloy with low and high Si contents, respectively. The microstructure of compositions with x=2.5 to 3.0 are mainly phase which is primary phase. The results were discussed with respect to the effect of cooling rate.

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Advanced Materials Research (Volumes 631-632)

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62-66

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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