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Calculation Model of Mass Action Concentration for CaO-B2O3-SiO2 Slag System

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Abstract:

According to the coexistence theory of melted slag structure, a calculation model of mass action concentrations for CaO-B2O3-SiO2 slag system has been established, by which the mass action concentrations of all structure units in CaO-B2O3-SiO2 systems are calculated. The results indicate that the activities of CaO and 2CaO•SiO2 can be decreased effectively by B2O3. Furthermore, when the slag basicity is higher than 2.0, the activity of 2CaO•SiO2 increases firstly and then decreases with the increasing of B2O3 content. The activity of CaO increases with the increasing of slag basicity. When the basicity is less than 2.2, the activity of 2CaO•SiO2 increases with the increase of slag basicity. Moreover, when the basicity is 2.2, the activity of 2CaO•SiO2 reaches the maximum value. In another word, the activity of 2CaO•SiO2 decreases with the increase of slag basicity on the condition that the slag basicity exceeds 2.2. B2O3 exists in the slag in the form of CaO•B2O3, 2CaO•B2O3 and 3CaO•B2O3.

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Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

3114-3117

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.3114

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Online since:

January 2013

Authors:

Hong Ming Wang, Xiang Zhu, Gui Rong Li

Keywords:

CaO-B2O3-SiO2 System, Coexistence Theory, Mass Action Concentration, Slag Structure

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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