Crystal Structure of bi(1,10-phenanthroline)- copper-Cl chlorine hydrate, [CuCl(C12H8N2)2]Cl0.5(H2O)5.5

Article Preview

Abstract:

A novel Cu metal complex [CuCl(C12H8N2)2]Cl 0.5(H2O)5.5 has been synthesized from a solution reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. [CuCl(C12H8N2)2]Cl 0.5(H2O)5.5, Monoclinic, C2/c. a=23.086(2)Å, b =30.090(3)Å, c=7.4580(8)Å, α=γ=90, β=97.67, V=5134.3Å3, Z=8, R1 =0.0923, wR2 =0.2182, T=298K. The crystal packing is stabilized by O-H...O and O-H...Cl hydrogen bonding and Л-Л interactions.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 634-638)

Pages:

3201-3204

Citation:

Online since:

January 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Conor S. Smith and Kent R. Mann. Void Space Containing Crystalline Cu(I) Phenanthroline Complexes As Molecular Oxygen Sensors. Chem. Mater., 2009, 21 (21), 5042–5049.

DOI: 10.1021/cm901109n

Google Scholar

[2] Heikki Korpi, Pawe J. Figiel, Elina Lankinen, Paul Ryan, Markku Leskelä, Timo Repo. On In Situ Prepared Cu-Phenanthroline Complexes in Aqueous Alkaline Solutions and Their Use in the Catalytic Oxidation of Veratryl Alcohol. European journal of inorganic chemistry, 2007, 17, 2465-2471.

DOI: 10.1002/ejic.200600908

Google Scholar

[3] Ivan I. Vorontsov, Tim Graber, Andrey Yu. Kovalevsky, Irina V. Novozhilova, Milan Gembicky, Yu-Sheng Chen and Philip Coppens. Capturing and Analyzing the Excited-State Structure of a Cu(I) Phenanthroline Complex by Time-Resolved Diffraction and Theoretical Calculations. J. Am. Chem. Soc., 2009, 131 (18), 6566–6573.

DOI: 10.1021/ja900921p

Google Scholar

[4] Tao Wang, Jun Peng, Hongsheng Liu, Dongxia Zhu, Aixiang Tian, Lixia Wang. Open framework complex constructed from polyoxometalate and dinuclear Cu-phenanthroline. Journal of molecular structure, 2008, 892(1-3), 268-271.

DOI: 10.1016/j.molstruc.2008.05.056

Google Scholar