Study on the Reaction Characteristics of Directional Synthesis of α-Terpineol from Turpentine

Abstract:

There was rarely high-purity α-terpineol or pure-monomer α-terpineol in China due to difficulty in isolating α-terpineol and γ-terpineol. Aiming at the separation problem, α-terpineol was directional synthesized by one-step method in a uniform system. The influence factors of stereochemistry structure, thermodynamic analysis and stability of reactants, products and carbocations were researched, conducting the experiments in optimal reaction conditions. All the influence factors about generating trend of objective product α-terpineol and byproduct γ-terpineol were discussed and the reaction mechanism was studied. This paper provided certain theoretical basis on prepare high-purity α-terpineol.

• Periodical: Advanced Materials Research (Volumes 634-638)
• Pages: 424-432
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.634-638.424
• Online since: January 2013
• Authors: Yan Gu, Zhen Dong Zhao, Jie Song, Dong Mei Li, Jing Wang, Yan Ju Lu, Liang Wu Bi
• Keywords: Reaction Mechanism, Stereochemistry Structure, Thermodynamic Analysis, α-Terpineol, γ-Terpineol

References

[1] Xiaopeng Chen, Yunming Zhang: Guangxi Chemical Industry (In Chinese), Vol. 21(3) (1992) p.4.

[2] Weiping Ban, Shiping Gao, Wenjing Song, et al: Chemistry and Industry of Forest Products (In Chinese), Vol. 21(1) (2001) p.75.

[3] Jinsheng Xie: Fujian Chemical Industry (In Chinese), Vol. 35(1) (2006) p.12.

[4] Bizeng Tang, Senshu Lin: Natural Gas Chemical Industry (In Chinese), Vol. 15(3) (1990) p.47.

[5] Lige Wang: Guangxi Chemical Industry (In Chinese), Vol. 19(4) (1990) p.27.

[6] Lige Wang, Yi Yang: Guangxi Chemical Industry (In Chinese), Vol. 20(4) (1991) p.12.

[7] Shitao Yu, Fusheng Liu, Congxia Xie, et al: Fine Chemicals (In Chinese), Vol. 21(3) (2004) p.178.

[8] Shitao Yu, Lu Li, Fusheng Liu, et al: Chemistry and Industry of Forest Products (In Chinese), Vol. 24(S) (2004) p.37.

[9] Yanming Wang, Tiancheng Liu, Meicun Zhou, et al: Chemistry and Industry of Forest Products (In Chinese), Vol. 24(S) (2004) p.57.

[10] Kai Zhu, Bin Xu, Gang Zhang: Chemistry and Industry of Forest Products (In Chinese), Vol. 25(4) (2005) p.38.

[11] Kai Zhu, Lianshan Mao, Xinbao Zhu: Petrochemical Technology (In Chinese), Vol. 35(1) (2006) p.60.

[12] Duangui Wu: Fujian Chemical Industry (In Chinese), Vol., 35(5) (2006) p.19.

[13] Zhendong Zhao, Dongmei Li, Liangwu Bi, et al, C.N. Patent, 101108788 B (2007).

[14] Fu'an Wang, Denggao Jiang: Chemical Data Guide (Chemical Industry Press, Beijing, China1995).

[15] S. W. Benson: Thermochemical Kinetics (John Wiley and Sons, New York, USA 1968).

[16] N. Cohen, S. W. Benson: Chem Reviews, Vol. 93(7) (1993) p.2419.

[17] S. W. Benson, F. R. Cruikshank, D. M. Golden, et a1: Chem Reviews, Vol. 69(3) (1969) p.279.

[18] Peisheng Ma: Chemical Data (China Petrochemical Press, Beijing, China 2003).

[19] Guangqi Liu, Lianxiang Ma, Jie Liu: Property Data Manual of Chemistry and Chemical Industry (inorganic volume) (Chemical Industry Press, Beijing, China 2002).

[20] Shimo Song, Gonghui Zhuang, Zhenglie Wang: Physical Chemistry (Higher Education Press, Beijing, China 1997).