Effect of Different Aromatic Carboxylic Acid Ligands on the Catalytic Activities of Metal-Organic Frameworks

Li Ping Wang; Gong Ying Wang; Fan Wang; Pin Hua Wang

doi:10.4028/www.scientific.net/AMR.634-638.513

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Effect of Different Aromatic Carboxylic Acid...

Effect of Different Aromatic Carboxylic Acid Ligands on the Catalytic Activities of Metal-Organic Frameworks

Abstract:

Metal-organic frameworks based on Zn2+ and different aromatic carboxylic acid ligands were prepared and characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. They were then used as the catalysts for the transesterification between diphenyl carbonate (DPC) and 1, 4-butyldiol (1, 4-BD) to polycarbonate diol (PCDL). Their catalytic activities in the transesterification process were evaluated by the yield of phenol, and their catalytic activities in the polycondensation process were determined by the number-average molecular weight (Mn) and the hydroxyl value.

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Advanced Materials Research (Volumes 634-638)

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513-517

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.634-638.513

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Online since:

January 2013

Authors:

Li Ping Wang, Gong Ying Wang, Fan Wang, Pin Hua Wang

Keywords:

Aromatic Carboxylic Acid, Catalyst, Diphenyl Carbonate, Metal-Organic Framework

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