Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

Jun Seong Park; Dae Hee Yun; Tae Won Ko; Yong Sung Park; Je Wan Woo

doi:10.4028/www.scientific.net/AMR.634-638.541

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Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 634-638Kinetic Study of the Diels-Alder Reaction of...

Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

Abstract:

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.