Preparation and Characterization of Polyaniline/PMN Composite by In Situ Polymerization Method

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Abstract:

The PANI/PMN composite was prepared by one-step in-situ polymerization method and was characterized via FT-IR, XRD, SEM and TG. The results indicate that the best reaction conditions of in-situ polymerization are 0°C/24h.The PMN powder are entirely coated with PANI, when composite contains more than 60% PANI by volume. The steric hindrance effect of PMN powder decreases the crystallization degree of PANI which polymerizes on the surface of PMN powder in the process of in-situ polymerization. The main weight loss occurring between 300 and 480°C corresponds to the degradation of the PANI polymer chain.

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230-233

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April 2009

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© 2009 Trans Tech Publications Ltd. All Rights Reserved

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