Synthesis of Copper Complexes of Poly [2-(dimethylamino ethyl methacrylate)-B-Poly (oligo (ethylene glycol) monomethylether methacrylate-B-Poly [2-(dimethylamino ethyl methacrylate)

Qian Qian You; Pu Yu Zhang

doi:10.4028/www.scientific.net/AMR.668.145

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 668Synthesis of Copper Complexes of Poly...

Synthesis of Copper Complexes of Poly [2-(dimethylamino ethyl methacrylate)-B-Poly (oligo (ethylene glycol) monomethylether methacrylate-B-Poly [2-(dimethylamino ethyl methacrylate)

Abstract:

Three different ratios of double hydrophilic block copolymers poly [2-(dimethylamino) ethyl methacrylate]-b-poly(oligo(ethylene oxide) monomethyl ether methacrylate)-b-poly [2-(dimethylamino) ethyl methacrylate] (PDMAEMA-b-POEOMA-b-PDMAEMA) were synthesized by reversible addition fragmentation chain-transfer polymerization (RAFT), which was one of the controlled/living radical polymerization. The chain structure and component of such copolymers were characterized by spectroscopic studies (FTIR, 1H NMR). The interaction of PDMAEMA-b-POEOMA-b-PDMAEMA copolymers with copper sulfate and copper chloride solution was studied. It was found that the anion SO42-, Cl-1 could have an effect on the structure and coordination of the Cu(II) complexes, which were confirmed by FTIR and scanning electron micrographs (SEM).

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Periodical:

Advanced Materials Research (Volume 668)

Pages:

145-148

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.668.145

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Online since:

March 2013

Authors:

Qian Qian You, Pu Yu Zhang

Keywords:

Complex, Copolymer, Double Hydrophilic

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