Study on the Preparation and Catalytic Property of Sulfonated Ordered Mesoporous Carbon

Xiang Jing Zhang; Yuan Yuan Wang; Cong Hao; Peng Tao Wu; Zi Chao Jiang

doi:10.4028/www.scientific.net/AMR.683.484

Paper Titles

The Research of the Application of Smart Coatings on Architectural Ornaments
p.464

Effects of Niobium and Titanium on the As-Cast Microstructure of Cr₈Mo₂VSi Cold Work Die Steel
p.468

Research on Sol-Gel Transition Process of Gelatin
p.474

Feasibility Study for Copper/Zirconium Oxides as Oxygen Carrier in Chemical Looping Air Separation (CLAS)
p.479

Study on the Preparation and Catalytic Property of Sulfonated Ordered Mesoporous Carbon
p.484

Research on Dynamic Recrystallization Behavior of 20CrMo Alloy Steel during Hot Deformation
p.488

Meshless Modeling of the Breakage Process of a Coal Prism within Vertical Roller Mills
p.492

Development and Application of Prediction Model for End-Point Manganese Content in Converter Based on Data from Sub-Lance
p.497

Effect of Sb Substitution on the Crystal Structure and Multiferroic Properties of BiFeO₃
p.504

HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 683Study on the Preparation and Catalytic Property of...

Study on the Preparation and Catalytic Property of Sulfonated Ordered Mesoporous Carbon

Abstract:

Sulfonated ordered mesoporous carbon (SOMC) has been used as a new catalytic material in heterogeneous reactions for it can replace many conventional homogeneous acid catalysts. At present, it was obtained mainly through sulfonating the surface of mesoporous carbon by post-processing method, which contained relatively complex process and rigorous condition. In this work, SOMC was prepared directly via pre-processing method. The structure and morphology of SOMC were characterized by means of FT-IR, XRD, TEM and BET, the catalytic performance was investigated by the acetalization reaction between benzaldehyde and n-butyl alcohol as a model reaction. The result showed that SOMC has excellent high surface area and uniform mesostructure when the mole ratio of phenolic resin: sulfuric acid: F127 was 1: 2: 0.0238 and carbonization temperature was 600°C. In the acetalization reaction, the yield of acetal of using SOMC material as catalyst was 87.1%, much higher than that of using HY zeolite, which shows that the SOMC has excellent catalytic property in the catalytic reaction of acetalization.