Activated Carbon Fiber Derived from Pyrolysis of Palm Fiber

Article Preview

Abstract:

Palm empty fruit bunch (EFB) is an abundant by-product resulted from massive palm oil production in Malaysia as one of the world's largest exporter and second largest producer of palm oil. This agricultural waste is usually disposed in nature, burnt in opened atmospheres, or used as a fuel for boilers. Such conventional handlings of EFB have created environmental concerns to Malaysia such as air pollution and release of green house gases (CH4 and CO2). This study made use of such biomass in the production of cost effective nanoporous material, namely activated carbon fiber (ACF) which able to diminish the problem of waste disposal, and at the same time to turn waste into wealth. This is especially beneficial when the ACF is used for environmental friendly application such as adsorbed natural gas (ANG) technology. ACF was formed from carbonaceous materials via process of carbonisation and activation. Both chemical and physical activations were carried out by using H2SO4 and CO2, respectively. In pyrolysis, carbonisation was conducted at temperatures i.e. 400, 600, 800 and 1000 °C in nitrogen (N2) atmosphere. Surface morphologies, microstructures, pore structures and surface chemistry of these samples were investigated for the characterisation of EFB fiber-derived ACF. Above 80% of the total pore volumes for the samples were contributed by the micropore as the major pore components in the ACF produced. The samples exhibited an high BET surface area , dominant micropore volume up and narrow pore size distribution in micro range (< 1.5 nm).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

92-103

Citation:

Online since:

April 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Mohammed, M.A.A., et al., Gasification of oil palm empty fruit bunches: A characterization and kinetic study. Bioresource Technology, 2012. 110(0): pp.628-636.

DOI: 10.1016/j.biortech.2012.01.056

Google Scholar

[2] Guo, J. and A.C. Lua, Effect of surface chemistry on gas-phase adsorption by activated carbon prepared from oil-palm stone with pre-impregnation. Separation and Purification Technology, 2000. 18: pp.47-55.

DOI: 10.1016/s1383-5866(99)00051-9

Google Scholar

[3] Eduardo J. Bottani and J.M.D. Tascón, eds. Adsorption by carbons. Adsorption on activated carbon fibers, ed. A. Linares-Salano and D. Cazorla-Amoros2008, Elsevier.

Google Scholar

[4] Carrott, P.J.M., et al., Preparation of activated carbon fibres from acrylic textile fibres. Carbon, 2001. 39(1543-1555).

DOI: 10.1016/s0008-6223(00)00271-2

Google Scholar

[5] Alcaniz-Monge, J., et al., Effect of the activating gas on tensile strength and pore structure of pitch-based carbon fibres. Carbon, 1994. 32(7): pp.1277-1283.

DOI: 10.1016/0008-6223(94)90113-9

Google Scholar

[6] Alcaniz-Monge, J., et al., Methane storange in activated carbon fibres. Carbon, 1997. 35(2): pp.291-297.

Google Scholar

[7] Lee, S.M. and K. Kaneko, Preparation of ultramicroporous carbon fiber of high adsorption capacity. Carbon, 2003. 41(2): pp.374-376.

DOI: 10.1016/s0008-6223(02)00361-5

Google Scholar

[8] Gao, F., et al., Preparation and hydrogen storage of activated rayon-based carbon fibers with high specific surface area Physics and Chemistry of Solids, 2010. 71(4): pp.444-447.

DOI: 10.1016/j.jpcs.2009.11.017

Google Scholar

[9] Im, J.S., et al., The study of controlling pore size on eectrospun carbon nanofibers for hyrogen adsorption. Calloid and Interface Science, 2008. 318(1): pp.42-49.

Google Scholar

[10] Derbyshire, F., et al., Synthesis of isotropic carbon fibers and activated carbon fibers from pitch precursors. Fuel, 2001. 80(3): pp.345-356.

DOI: 10.1016/s0016-2361(00)00099-5

Google Scholar

[11] Asakura, R., et al., Preparation of fibrous activated carbons from wood fiber. Materials Science, 2004. 39(1): pp.201-206.

DOI: 10.1023/b:jmsc.0000007745.62879.74

Google Scholar

[12] Alam, M.Z., et al., Activated carbons derived from oil palm empty-fruit bunches: Application to environmental problems. Journal of Environmental Sciences, 2007. 19(1): pp.103-108.

DOI: 10.1016/s1001-0742(07)60017-5

Google Scholar

[13] Arami-Niya, A., et al., Production of microporous palm shell based activated carbon for methane adsorption: Modeling and optimization using response surface methodology. Chemical Engineering Research and Design, 2011(0).

DOI: 10.1016/j.cherd.2011.10.001

Google Scholar

[14] Arami-Niya, A., W.M.A.W. Daud, and F.S. Mjalli, Comparative study of the textural characteristics of oil palm shell activated carbon produced by chemical and physical activation for methane adsorption. Chemical Engineering Research and Design, 2011. 89 (6): pp.657-664.

DOI: 10.1016/j.cherd.2010.10.003

Google Scholar

[15] Lillo-Ródenas, M.A., et al., Activated carbons prepared by pyrolysis of mixtures of carbon precursor/alkaline hydroxide. Journal of Analytical and Applied Pyrolysis, 2007. 80(1): pp.166-174.

DOI: 10.1016/j.jaap.2007.01.014

Google Scholar

[16] Moran, J.I., et al., Extraction of cellulose and preparation of nanocellulose from sisal fibers. . Cellulose, 2008. 15(1): pp.149-159.

DOI: 10.1007/s10570-007-9145-9

Google Scholar

[17] Guo, J. and A.C. Lua, Characterization of adsorbent prepared from oil-palm shell by CO2 activation for removal of gaseous pollutants. Materials Letters, 2002. 55(5): pp.334-339.

DOI: 10.1016/s0167-577x(02)00388-9

Google Scholar

[18] Yang, H., et al., Characteristics of hemicellulose, cellulose and lignin pyrolysis Fuel, 2007. 86(12-13): pp.1781-1788.

DOI: 10.1016/j.fuel.2006.12.013

Google Scholar

[19] Stuart, B.H., Infrared Spectroscopy: Fundamentals and Applications2004, UK: John Wiley and Sons, Ltd.

Google Scholar

[20] Bilba, K. and A. Ouensanga, Fourier transform infrared spectroscopic study of thermal degradation of sugar cane bagasse. Analytical and Applied Pyrolysis, 1996. 38(1-2): pp.61-73.

DOI: 10.1016/s0165-2370(96)00952-7

Google Scholar

[21] Ahmad, A.L., M.M. Loh, and J.A. Aziz, Preparation and characterization of activated carbon from oil palm wood and its evaluation on Methylene blue adsorption. Dyes and Pigments, 2007. 75(2): pp.263-272.

DOI: 10.1016/j.dyepig.2006.05.034

Google Scholar

[22] Lua, A.C. and T. Yang, Properties of pistachio-nut-shell activated carbons subjected to vacuum pyrolysis conditions. Carbon, 2004. 42(1): pp.224-226.

DOI: 10.1016/j.carbon.2003.09.013

Google Scholar

[23] Linares-Solano, A., et al., Activated carbons from bituminous coal: effect of mineral matter content. Fuel, 2000. 79(6): pp.635-643.

DOI: 10.1016/s0016-2361(99)00184-2

Google Scholar

[24] Linares-Solano, A. and D. Cazorla-Amoros, Adsorption on activated carbon fibers. Adsorption by carbons, 2008: pp.431-454.

DOI: 10.1016/b978-008044464-2.50021-3

Google Scholar

[25] Valix, M., W.H. Cheung, and K. Zhang, Role of chemical pre-treatment in the development of super-high surface areas and heteroatom fixation in activated carbons prepared from bagasse. Microporous and Mesoporous Materials, 2008. 116(1-3): pp.513-523.

DOI: 10.1016/j.micromeso.2008.05.020

Google Scholar

[26] Cuerda-Correa, E.M., et al., Preparation of activated carbons previously treated with sulfuric acid. A study of their adsorption capacity in solution. Applied Surface Science, 2006. 252(17): pp.6042-6045.

DOI: 10.1016/j.apsusc.2005.11.013

Google Scholar

[27] Guo, J. and A.C. Luo, Characterization of adsorbent prepared from oil-palm shell by CO2 activation for removal of gaseous pollutants. Materials Letters, 2002. 55(5): pp.334-339.

DOI: 10.1016/s0167-577x(02)00388-9

Google Scholar

[28] Shao, X., W. Wang, and X. Zhang, Experimental measurement and computer simulation of methane adsorption on activated carbon fibers. carbon, 2007. 45(1): pp.188-195.

DOI: 10.1016/j.carbon.2006.07.006

Google Scholar