Advanced Materials Research Vols. 690-693

Abstract: In this paper,we used the heavy oil of Du 84,53-55 well in Liaohe oil field,analyzed of the impact factors of the heavy oil emulsion viscosity.When the droplet size of the emulsion is reduced,the viscosity of the heavy oil emulsion increases,and the non-Newtonian obvious.Heavy oil emulsions exhibit Newtonian fluid properties at low shear rate,exhibits shear-thinning properties in the heavy oil emulsion under high shear rate.Heavy oil emulsion viscosity decreases with the increasing concentration of viscosity reducer,when the viscosity reducer concentration of more than 0.25%,heavy oil emulsion viscosity declines slowed.

Abstract: The decolorization kinetic of C.I. Reactive Black 5 was studied using Fenton-like oxidation. The effect of the major system parameters, such as initial pH of the solution, concentration of H2O2, concentration of Fe3+ and reaction temperature on the kinetics was determined. The results indicate that the operating parameters, such as initial pH of dye solution, initial concentration of Fe2+ and H2O2, reaction temperature, have strong influences on the degradation of C.I. Reactive Black 5 by Fenton-like oxidation process. In addition, it was also found that the decolorization of C.I. Reactive Black 5 followed the first-order kinetics well.

Abstract: For natural gas well in sour gas reservoirs, very serious corrosion in the gas well string is an important factor of gas production system life. In order to ensure the long-term development of gas wells, this paper mainly introduces the tubing and casing corrosion in sour gas reservoirs, corrosion-resistant material selection of tubing and casing in sour gas reservoirs and proposes the optimization idea and technique of tubing material selection.. By taking W 63 well as an example, this paper optimizes the material selection of production casing for W 63 well. For application, the optimal materials of gas well string in W 63 well have good performance of corrosion resistance.

Abstract: Material selection of water-ring vacuum pumps in the chemical industry is closely related to the suction gas medium composition. Using the case of 70,000 tons of sodium yellow phosphorus tail gas system of water-ring vacuum pump in Guizhou Kaiyang Qingli tianmeng Chemical Ltd. (hereafter abbreviation as Tianmeng Company), this paper introduces vacuum pump in the production process of yellow phosphorus tail gas, according to the characteristics of corrosion in acidic media on flow passage component, and analyze the factors influencing the selection of materials from the point of view of the production process of yellow phosphorus tail gas.

Abstract: This paper reports a novel coprecipitation process for the preparation of strontium-barium hydroxyapatite [Sr_5-xBa_x(PO₄)₃OH]. Strontium nitrate, barium nitrate and phosphoric acid were dissolved in water to form a homogeneous Sr-Ba-P aqueous solution. The samples were characterized by powder X ray diffraction, Fourier transformed infrared spectroscopy and scanning electron microscopy. The results showed that the barium phosphate [Ba₃(PO₄)₂] phase appeared at the samples prepared at the pH value lower than 12. A series of Sr_5-xBa_x(PO₄)₃OH samples had beenobtained by adding sodium hydroxide aqueous solution into the Sr-Ba-P solution to pH12.5 and following aging at 60 °C for 24h. The so-prepared samples are metallic cation-deficient hydroxyapatite solid solutions. The samples present low degree of crystallinity, irregular short rod-like morphology and nanometer size. The crystal cell parameters of Ca_5-xSr_x(PO₄)₃OH samples are nearly linear to their barium content, and their infrared absorption bands of PO₄^3- groups shift to lower wave numbers with the increase of the barium content.

Abstract: A series of CuO-ZnO-Al₂O₃ catalysts modified by different promoter were prepared by co-precipitation or incipient wet impregnation and characterized by X-ray diffraction (XRD), N₂ physisorption, hydrogen temperature-programmed reduction (H₂-TPR) and carbon dioxide temperature-programmed desorption (CO₂-TPD). The modified catalysts were tested for methanol synthesis from CO/CO₂ co-hydrogenation in a fixed bed reactor with feed containing CO, CO₂ and H₂(CO:CO₂:H₂=1.0:1.08:6.24, volume radio). It is revealed that the catalysts modified by Zr, Mg, Ca has higher activity of methanol synthesis by CO and CO₂ co-hydrogenation. Especially, the addition of Zr enhances the conversion of total carbon and the selectivity of methanol, which is due to the improved surface area, much more active sites, and the synergistically interaction between CuO and ZnO caused by the addition of Zr promoter.

Abstract: An investigate was carried out to evaluate the catalytic performance of Fe, Al-pillared bentonite in heterogeneous UV-Fenton process. The catalysts were prepared by a cation doping technique. X-ray diffiraction and infraed spectroscopy were used to characterize their properties. Results showed that intercalated process could obtained larger interlayer spacing. Some bands of infrared spectroscopy shifted to lower wave length, indicating that Fe_xAl_y has intercalated into the layers of the bentonite. The higher ratio of Fe to Al was in the pillaring solution, the higher discolouration rate could be obtained. The discoloration rate reached 79.9% at 20 min and 283K when the ratio of Fe to Al in pillaring solution was 9:1. The reaction constants of the heterogeneous UV-Fenton process increased from 0.074 min^-1 at 283K to 0.094min^-1 at 323K. Its activation energy was 36.7kJ.mol^-1, indicating that temperature had little effect on this process. Little Fe-leaching made it possible for Fe, Al-pillared bentonite to remain a high stability during recycling uses.

Abstract: Most studies about urban street dust have been focused on big cities so far and less attention has been focused on small towns. In this paper, we collected 12 samples from four different localities (Commercial Area, Industrial Area, Shuangzhu Street, Xuefu Road) in small towns of Yongchuan District, Chongqing to investigate the concentration distribution and composition of nitrogen in street dust. The results revealed that dust samples from Commercial Area contain higher concentration of total nitrogen (TN) (e.g., 1672mg/kg) comparing with dust samples from other three sites (e.g., 196-682mg/kg). In addition, inorganic nitrogen was the predominant form in every site and accounted for 67%-89% of TN. Organic carbon (OC) and pH also had an effect on concentration and composition of TN.

Abstract: In this paper, the characteristics o f trace metal elements were studied in Elsholtzia harchowensis. The relation of trace elements between plant and soil was studied, and the copper tolerance and mechanism of the plant was discussed in details. The results showed that the trace element contents of the soil was higher, Cu content was highest in these elements, and it was as more 200 times as that of control sites. Cu in the plant was highest in these elements and Cd was lowest. The elements sequence in plant was: Cu> Mn> Zn> Pb> Cd. Element contents in different parts of the plant were: Cu, root> flower> leaf> stem; Cd, leaf> flower> root> stem; Mn, leaf> root > flower> stem; Zn, leaf> flower> stem> root; Pb, root> leaf> stem> flower. There is positive correlation in Cu between plant and soil. The tolerance capacity is higher in the plant.

Abstract: In order to improve the dyeing property of cotton fiber, in this paper, the cotton fabric was modified by 2, 3-epoxpropyl triethyl ammonium chloride (ETEAC). Four reactive dyes were employed to test the dyeing property of modified cotton fabric. The results showed that the dyeing property of cotton fabric was improved greatly. When the concentration of ETEAC was equal to or above 7%, most of the dye-uptake rate of the modified cotton fabric could reach to nearly 100%. And the dyeing rate was very high. These suggested that the cationic groups with three ethyls could attract anion dyes efficiently, though the cationic groups with three ethyls were greater than cationic groups with three methyls. The modified cotton fabric could not be dyed uniformly. Sodium dodecyl sulfate (SDS) was efficient retarder for the modified cotton fabric.